Room-temperature ionic liquids (RTILs) with polymerizable groups can be readily converted into solid, dense poly(RTILs) for use as gas separation membranes. A series of RTIL monomers with varying length n-alkyl substituents were synthesized and converted into polymer films. These membranes were tested for their performance in separations involving CO 2 , N 2 , and CH 4 . CO 2 permeability was observed to increase in a nonlinear fashion as the n-alkyl substituent was lengthened. CO 2 /N 2 separation performance was relatively unaffected as CO 2 permeability increased. Plotting the performance of these membranes on a "Robeson plot" for CO 2 /N 2 shows that first-generation poly(RTILs) "hug" the "upper bound" of the chart, indicating that they perform as well or better than many other polymers for this separation. The CO 2 /CH 4 separation is less impressive when compared to other polymer membranes on a "Robeson plot", but poly(RTILs) perform as well or better than molten RTILs do in bulk fluid gas absorptions for that gas pair. Furthermore, poly(RTILs) were determined to be able to absorb about twice as much CO 2 as their liquid analogues, an important factor which may give them potential use as gas and vapor sorbents.

Novel imidazolium-based room-temperature ionic liquids (RTILs) with one, two, or three oligo(ethylene glycol) substituents were synthesized. Solubilities and ideal solubility selectivities of CO 2 , N 2 , and CH 4 at low pressure (1 atm) in these RTILs were determined using a pressure decay technique. Comparison to corresponding alkyl analogues of these RTILs reveals similar levels of CO 2 solubility but lower solubilities of N 2 and CH 4 . As a consequence, RTILs with oligo(ethylene glycol) substituents were observed to have 30-75% higher ideal solubility selectivities for CO 2 /N 2 and CO 2 /CH 4 .

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