Transition metal dichalcogenides (TMDs) such as MoSe2 have continued to generate interest in the engineering community because of their unique layered morphology—the strong in-plane chemical bonding between transition metal atoms sandwiched between two chalcogen atoms and the weak physical attraction between adjacent TMD layers provides them with not only chemical versatility but also a range of electronic, optical, and chemical properties that can be unlocked upon exfoliation into individual TMD layers. Such a layered morphology is particularly suitable for ion intercalation as well as for conversion chemistry with alkali metal ions for electrochemical energy storage applications. Nonetheless, host of issues including fast capacity decay arising due to volume changes and from TMD’s degradation reaction with electrolyte at low discharge potentials have restricted use in commercial batteries. One approach to overcome barriers associated with TMDs’ chemical stability functionalization of TMD surfaces by chemically robust precursor-derived ceramics or PDC materials, such as silicon oxycarbide (SiOC). SiOC-functionalized TMDs have shown to curb capacity degradation in TMD and improve long term cycling as Li-ion battery (LIBs) electrodes. Herein, we report synthesis of such a composite in which MoSe2 nanosheets are in SiOC matrix in a self-standing fiber mat configuration. This was achieved via electrospinning of TMD nanosheets suspended in pre-ceramic polymer followed by high temperature pyrolysis. Morphology and chemical composition of synthesized material was established by use of electron microscopy and spectroscopic technique. When tested as LIB electrode, the SiOC/MoSe2 fiber mats showed improved cycling stability over neat MoSe2 and neat SiOC electrodes. The freestanding composite electrode delivered a high charge capacity of 586 mAh g-1electrode with an initial coulombic efficiency of 58%. The composite electrode also showed good cycling stability over SiOC fiber mat electrode for over 100 cycles.

Transition metal dichalcogenides (TMDs) such as the WS2 have been widely studied as potential electrode materials for lithium-ion batteries (LIB) owing to TMDs’ layered morphology and reversible conversion reaction with the alkali metals between 0 to 2 V (v/s Li/Li+) potentials. However, works involving TMD materials as electrodes for sodium- (NIBs) and potassium-ion batteries (KIBs) are relatively few, mainly due to poor electrode performance arising from significant volume changes and pulverization by the larger size alkali-metal ions. Here, we show that Na+ and K+ cyclability in WS2 TMD is improved by introducing WS2 nanosheets in a chemically and mechanically robust matrix comprising precursor-derived ceramic (PDC) silicon oxycarbide (SiOC) material. The WS2/SiOC composite in fibermat morphology was achieved via electrospinning followed by thermolysis of a polymer solution consisting of a polysiloxane (precursor to SiOC) dispersed with exfoliated WS2 nanosheets. The composite electrode was successfully tested in Na-ion and K-ion half-cells as a working electrode, which rendered the first cycle charge capacity of 474.88 mAh g−1 and 218.91 mAh g−1, respectively. The synergistic effect of the composite electrode leads to higher capacity and improved coulombic efficiency compared to the neat WS2 and neat SiOC materials in these cells.

Layered transition metal dichalcogenides (TMDs) such as tungsten disulfide (WS 2 ) are promising materials for a wide range of applications, including charge storage in batteries and supercapacitors. Nevertheless, TMD-based electrodes suffer from bottlenecks such as capacity fading at high current densities, voltage hysteresis during the conversion reaction, and polysulfide dissolution. To tame such adverse phenomena, we fabricate composites with WS 2 nanotubes. Herein, we report on the superior electrochemical performance of ceramic composite fibers comprising WS 2 nanotubes (WS 2 NTs) embedded in a chemically robust molecular polymer-derived ceramic matrix of silicon-oxycarbide (SiOC). Such a heterogeneous fiber structure was obtained via electrospinning of WS 2 NT/preceramic polymer solution followed by pyrolysis at elevated temperatures. The electrode capacity fading in WS 2 NTs was curbed by the synergistic effect between WS 2 NT and SiOC. As a result, the composite electrode exhibits high initial capacity of 454 mAh g -1 and the capacity retention approximately 2-3 times higher than that of the neat WS 2 NT electrode.

The superior properties, such as large interlayer spacing and the ability to host large alkali-metal ions, of two-dimensional (2D) materials based on transition metal di-chalcogenides (TMDs) enable next-generation battery development beyond lithium-ion rechargeable batteries. In addition, compelling but rarely inspected TMD alloys provide additional opportunities to tailor bandgap and enhance thermodynamic stability. This study explores the sodium-ion (Na-ion) and potassium-ion (K-ion) storage behavior of cation-substituted molybdenum tungsten diselenide (MoWSe2), a TMD alloy. This research also investigates upper potential suspension to overcome obstacles commonly associated with TMD materials, such as capacity fading at high current rates, prolonged cycling conditions, and voltage polarization during conversion reaction. The voltage cut-off was restricted to 1.5 V, 2.0 V, and 2.5 V to realize the material’s Na+ and K+ ion storage behavior. Three-dimensional (3D) surface plots of differential capacity analysis up to prolonged cycles revealed the convenience of voltage suspension as a viable method for structural preservation. Moreover, the cells with higher potential cut-off values conveyed improved cycling stability, higher and stable coulombic efficiency for Na+ and K+ ion half-cells, and increased capacity retention for Na+ ion half-cells, respectively, with half-cells cycled at higher voltage ranges.

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