Solution-processed indium gallium tin oxide (InGaSnO, IGTO) thin film transistors (TFTs) are investigated as promising low-cost and stable materials for high-performance amorphous oxide semiconductor (AOS)-based TFTs in display applications. After tailoring the metal cation composition in IGTO thin films, the IGTO (7:1:1) AOS TFT shows a saturation mobility and current on/off ratio of 2.13 cm 2 V −1 s −1 and 2.55 × 10 7 , superior to the IGZO TFT. It was found that the threshold voltage (V th ) shifts of IGTO TFTs with higher Sn molar ratios became gradually diminished both under the positive bias stress (PBS) test, from +7.3 to +1.1 V, and under the negative bias stress (NBS) test, from −2.83 to −0.94 V, due to the increased concentration of Sn−O complexes with relatively higher bonding energies within IGTO thin films. X-ray photoelectron spectroscopy (XPS) analysis also reveals that IGTO thin films with higher Sn composition ratio tend to effectively suppress the formation of oxygen vacancy, which consequently led to the improved stability of IGTO-based TFTs under the gate bias stress. Therefore, these results can be the basis for improving the characteristics of IGTO semiconducting channel systems for low-cost switching devices in the display applications.
This experimental study reveals the presence of mainly two-fold positively charged aluminium complexes in NMA : Al(TfO)3 : urea mixtures caused by bidentate hydrogen bonding between Al triflate and urea at a specific 1 : 4 ratio.
At present, carbon dioxide (CO 2 ) emission, which causes global warming, is a major issue all over the world. To reduce CO 2 emission directly, commercial deployment of CO 2 separation processes has been attempted in industrial plants, such as power plant, oil refinery and steelmaking plant. Besides, several studies have been done on indirect reduction of CO 2 emission from recycle of reducing gas (carbon monoxide or hydrogen containing gas) in the plants. Unlike many competing gas separation technologies, pressure swing adsorption (PSA) and membrane filtration are commercially used together or individually to separate a single component from the gas mixture. However, there are few studies on operation of sequential separation process of multi-component gas which has more than two target gas † To whom correspondence should be addressed.
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