Precious metal oxides exhibit impressive characteristics that caught worldwide attention due to their promising capacitive performance, excellent electrochemical stability and low resistance, and these metal oxides have been extensively employed in supercapacitor application. This type of supercapacitors is known as redox supercapacitors or pseudocapacitors which applied faradaic process in storing energy in their systems. Thus, new materials with impressive electrochemical performance are highly demanded. In this aspect, cobaltite system with spinel structure has been the subject of intense research due to its established applications in electrochemistry. Besides, carbonaceous materials like activated carbons, carbon nanotubes, graphites, graphenes and fullerenes utilize electric double-layer capacitance whereby energy is stored by charge separation at an electrode/electrolyte interface. With greater development conducted on metal oxides and carbonaceous materials for supercapacitor application, introduction of hybrid and composite electrodes comprise of these two types of materials have been well received.

No abstract

High density and vertically aligned zinc oxide nanorod arrays (ZnO NRs) have been prepared directly on indium-doped tin oxide (ITO) substrates via two-steps preparation: sol-gel spin coating and hydrothermal process. The nanostructured ZnO was characterized for its morphology, crystalline structure and optical properties by using field emission scanning electron microscopy (FESEM), X-ray diffractometry, and ultraviolet-visible spectroscopy respectively. In addition, the photoeletrochemical (PEC) properties were investigated through photocurrent measurements. The ZnO NRs/ITO had wurtzite-structured (hexagonal) ZnO and preferred growth along (0001) direction. When the growth time was 4 h, ZnO NRs/ITO showed impressive photoresponse. The PEC analysis verified that the ZnO NRs gave better photocurrent response and photoconversion efficiency with approximately 42 times greater than seed layer.

No abstract

Particular interest has been given to the self-organized titania nanotube TiO 2 thin films prepared by using anodisation method followed by annealing in the air, while the CdSe layer was potentiostatically electrodeposited onto the TiO 2 nanotube films at various pH. The resulting films were studied by using energy dispersive X-ray spectroscopy, X-ray diffraction, field emission scanning electron microscopy, UV-Vis spectroscopy and photoelectrochemical analysis to characterize their compositional, crystalline structure, surface morphological, optical, and photoconversion efficiency characteristics. The resulting CdSe/TiO 2 nanotube exhibits significant enhancement in optical absorption, photocurrent density and photoconversion efficiency. CdSe/TiO 2 nanotube prepared at pH 3 exhibited the highest photocurrent density of 2.13 mA cm −2 and photoconversion efficiency of 1.02 % which is 51 times higher than TiO 2 nanotube array. This may due to the formation of CdSe nanocrystals which were well crystallized and bonded with TiO 2 NTAs contributing to the enhanced photoresponse and photostability of the overall performance of CdSe/TiO 2 NTAs heterostructures.