We
demonstrate a simple, nonlithographic method for fabricating piezoresistive
pressure sensors with a broad range of working pressures and low detection
limit. Our wearable pressure sensor is fabricated by using two metallized,
porous polymer layers which undergo a change in resistance as a function
of pressure. This sensor has a sandwich structure composed of top
and bottom sheets of porous polydimethylsiloxane (PDMS) fabricated
by using a simple templating method. The inner face of each of these
layers is coated with a layer of conductive silver nanowires (AgNWs).
The AgNW layers are initially in light contact, and the device undergoes
a change in resistance when pressure is applied perpendicular to the
plane of the sheets. In these devices, the size of the pores is an
important determinant of the device sensitivity and range. Powder
templates of KCl, NaCl, and sugar are used to create different sized
pores (60–90, 200–275, and 400–550 μm,
respectively) in the elastomeric PDMS layers, which in turn affects
the mechanical deformability of the devices. The sensors fabricated
with KCl porous layers (which had the smallest pores) demonstrate
the best performance, with a sensitivity of 14.1 kPa–1 (up to 3.5 kPa), 4.8 kPa–1 (up to 10 kPa), and
1.84 kPa–1 (up to 40 kPa) and good stability over
1000 loading and unloading cycles. Pressure sensors are also fabricated
by decreasing the ratio of PDMS base to curing agent from the standard
10:1 formulation, which increases the stiffness of the viscoelastic
PDMS layer and thus shortens the response time. The stiffest formulation
(5:1 (base:curing agent)) sample gives the shortest response time
of ∼47 ms. Wearable electronic applications of these devices,
including pulse measurement, facial movements, and sound tracking,
are demonstrated in this work.
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