In this study, the potential of a new low-cost adsorbent, Syringa vulgaris leaves powder, for methylene blue adsorption from aqueous solution was investigated. The adsorbent surface was examined using SEM and FTIR techniques. The experiments were conducted, in batch system, to find out the effect of pH, contact time, adsorbent dose, initial dye concentration, temperature and ionic strength on dye adsorption. The process is best described by Langmuir isotherm and the pseudo second order kinetic model. Maximum adsorption capacity, 188.2 (mg g−1), is better than other similar adsorbent materials. Thermodynamic parameters revealed a spontaneous and endothermic process, suggesting a physisorption mechanism. A Taguchi orthogonal array (L27) experimental design was used to determine the optimum conditions for the removal of dye. Various desorbing agents were used to investigate the regeneration possibility of used adsorbent. Results suggest that the adsorbent material is very effective for removal of methylene blue from aqueous solutions.
One of the most serious problems of the food industry is lipid oxidation, which decreases nutritional quality, increases toxicity, and alters texture and color of the food in question. Research suggests that oxidation of lipids from the diet may play a direct role in the development of chronic diseases in the human body. Natural antioxidants may be added directly to foods as primary antioxidants, which donate hydrogen atoms to quench peroxyl radicals before they can further react with unsaturated lipids. Antioxidants significantly extend the shelf life of foods containing lipids susceptible to oxidation such as vegetable oils. Wild berries are a potential source of natural anthocyanin antioxidants. This paper presents experimental results obtained using antocyanins from Vaccinium Vitis - Idaea Fruits, upon color and thermal properties of sesame food oil, which was exposed to UV radiation.
In this work, raspberry (Rubus idaeus) leaves were converted to powder and used as a new natural lignocellulosic low-cost adsorbent for methylene blue removal from aqueous solutions. Different techniques (FTIR, SEM, color analysis, and pHPZC determination) were applied for adsorbent characterization. The effects of pH, ionic strength, contact time, adsorbent dose, initial deconcentration, and temperature on adsorption capacity were investigated. Equilibrium, kinetic, and thermodynamic studies have shown that the adsorption is best described by the Sips isotherm and pseudo-second-order kinetic model and that the process is spontaneous, favorable, and endothermic, involving physisorption as the main mechanism. The maximum adsorption capacity was 244.6 (mg g−1) higher compared to other adsorbents based on plant leaves. The Taguchi method and the ANOVA analysis were used to optimize the adsorption conditions. The contact time was the factor with the highest influence on the process, while the temperature had the lowest influence. A desorption study was also performed to determine the possibility of adsorbent regeneration.
The aim of this study is the rapid detection of food pressed oils adulteration with their refined versions, using UV–Vis spectroscopy. The study investigates some common oil physico-chemical parameters such are: density, viscosity, refractive index, acid index, peroxide value, saponification index, to detect differences between cold pressed oils versus refined ones, for some food-grade oils found on Romanian market, as well as FT-IR spectroscopy and GC–MS analytical method, obtaining similar results to those presented in the literature data. The difference between some of the obtained results is not relevant for telling the cold-pressed oils from their refined version for adulteration investigation purpose. Colour analysis instead is a very good method to differentiate a cold pressed oil from a refined one. Taking this into account, the cold pressed oils and their refined versions were mixed in different proportions, and their colour properties were analyzed, obtaining linear dependences for a* and b* CIE L*a*b* parameters with cold pressed oil content in the mixture. Dependence equations were proposed.
BACKGROUND: In the circular economy context, the present article proposes a green technical solution by manganese ions adsorption on oak wood ash and the reuse of the new waste generated by the adsorption process as soil amendment. RESULTS:The influence of the main process variables: pH, adsorbent dose and contact time was investigated for optimal manganese ions adsorption. The highest adsorption efficiency of the wood ash (more than 98%) was recorded at pH 6, adsorbent dose of 10 g L −1 and contact time 15 min. The ion adsorption process is best described by Langmuir isotherm and pseudo second-order kinetic model. Maximum adsorption capacity, 54.94 mg g −1 , is better than other adsorbent materials previously used for manganese adsorption. The exhausted wood ash, resulted after the manganese adsorption was used as soil amendment for barley crop, Hordeum vulgare L. The beneficial effect upon the studied plants was highlighted using the specific parameters: germination percent (up to 10% higher), plant average length (higher by 14-35%), biomass (up to 200%) and relative growth rate (higher by 6-12%) compared to those obtained for the control sample.CONCLUSION: These results show that all the wastes involved have been used successfully and support the proposed ecofriendly technical solution for some industrial wastes management.
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