We present geometric derivations of the Smarr formula for static AdS black holes and an expanded first law that includes variations in the cosmological constant. These two results are further related by a scaling argument based on Euler's theorem. The key new ingredient in the constructions is a two-form potential for the static Killing field. Surface integrals of the Killing potential determine the coefficient of the variation of Λ in the first law. This coefficient is proportional to a finite, effective volume for the region outside the AdS black hole horizon, which can also be interpreted as minus the volume excluded from a spatial slice by the black hole horizon. This effective volume also contributes to the Smarr formula. Since Λ is naturally thought of as a pressure, the new term in the first law has the form of effective volume times change in pressure that arises in the variation of the enthalpy in classical thermodynamics. This and related arguments suggest that the mass of an AdS black hole should be interpreted as the enthalpy of the spacetime. 5 The volume element dS ab is specified in more detail by writing out Gauss' law for A c = ∇ b B bc as Σ dvn c A c = ∂Σ∞ dar b n c B bc − ∂Σ h dar b n c B bc where n a is the unit normal to Σ and r b is the unit normal to ∂Σ within Σ taken to point towards infinity. Therefore, we have for the surface volume element dS bc = 2dar [b n c] . Note that throughout the paper, we will take n a to be future pointing.

We present a new cubic theory of gravity in five dimensions which has second order traced field equations, analogous to BHT new massive gravity in three dimensions. Moreover, for static spherically symmetric spacetimes all the field equations are of second order, and the theory admits a new asymptotically locally flat black hole. Furthermore, we prove the uniqueness of this solution, study its thermodynamical properties, and show the existence of a C-function for the theory following the arguments of Anber and Kastor (arXiv:0802.1290 [hep-th]) in pure Lovelock theories. Finally, we include the Einstein-Gauss-Bonnet and cosmological terms and we find new asymptotically AdS black holes at the point where the three maximally symmetric solutions of the theory coincide. These black holes may also possess a Cauchy horizon.

We study properties of static, asymptotically AdS black holes in Lovelock gravity. Our main result is a Smarr formula that gives the mass in terms of geometrical quantities together with the parameters of the Lovelock theory. As in Einstein gravity, the Smarr formula follows from applying the first law to an infinitesimal change in the overall length scale. However, because the Lovelock couplings are dimensionful, we must first prove an extension of the first law that includes their variations. Key ingredients in this construction are the KillingLovelock potentials associated with each of the higher curvature Lovelock interactions. Geometric expressions are obtained for the new thermodynamic potentials conjugate to variation of the Lovelock couplings.

Entanglement entropy in conformal field theories is known to satisfy a first law. For spherical entangling surfaces, this has been shown to follow via the AdS/CFT correspondence and the holographic prescription for entanglement entropy from the bulk first law for Killing horizons. The bulk first law can be extended to include variations in the cosmological constant Λ, which we established in earlier work. Here we show that this implies an extension of the boundary first law to include varying the number of degrees of freedom of the boundary CFT. The thermodynamic potential conjugate to Λ in the bulk is called the thermodynamic volume and has a simple geometric formula. In the boundary first law it plays the role of a chemical potential. For the bulk minimal surface Σ corresponding to a boundary sphere, the thermodynamic volume is found to be proportional to the area of Σ, in agreement with the variation of the known result for entanglement entropy of spheres. The dependence of the CFT chemical potential on the entanglement entropy and number of degrees of freedom is similar to how the thermodynamic chemical potential of an ideal gas depends on entropy and particle number.

We classify all the six derivative Lagrangians of gravity, whose traced field equations are of second or third order, in arbitrary dimensions. In the former case, the Lagrangian in dimensions greater than six, reduces to an arbitrary linear combination of the six dimensional Euler density and the two linearly independent cubic Weyl invariants. In five dimensions, besides the independent cubic Weyl invariant, we obtain an interesting cubic combination, whose field equations for static spherically symmetric spacetimes are of second order. In the later case, in arbitrary dimensions we obtain two combinations, which in dimension three, are equivalent to the complete contraction of two Cotton tensors. Moreover, we also recover all the conformal anomalies in six dimensions. Finally, we present the general static, spherically symmetric solution for some of these Lagrangians.1 Note that the only non-quadratic term with degree of differentiation 4 is R, which is boundary term. 2 Since a divergenceless vector J a cannot be constructed locally out of the curvature, the equation ∇aJ a = 0, with J a := ∇ b −4aR ab + g ab 4a + D 2 b + 2(D − 1)c R , does not have any non-trivial solution.