There are considerable differences between the EU-15 countries and Central and Eastern European (CEE) countries in the application rate of phosphorus (P) fertilizer and manure as well as in the climate and erosion patterns, but the eutrophication of surface waters is a common problem. The availability of information on the contribution of the CEE countries to European surveys on eutrophication is not adequate, because the amount of data available from these countries is small. There is thus a need to compile more comprehensive data sets for better assessment. Recent changes in agricultural practices, and their impact on the trophic status of surface waters in CEE countries, have been evaluated using a few selected pressure and state indicators (phosphorus balance, phosphorus status and erosion of agricultural land, P loss risk index, chlorophyll a, total and orthophosphate content of water) by compiling and analysing data from the literature. In the CEE countries, small annual P balances ()7 to +6 kg P ha )1 ) and declining levels of soil available P (proportion of soils adequately supplied with P dropped to between 10 and 50% of total area) may lead to low yields and economic difficulties. Only 11% of the variation in total phosphorus (TP) in rivers studied could be attributed to the calculated P loss risk index, and thus to the impact of differences in the agricultural diffuse source P load. The generation of more consistent data sets should be pursued for the whole of Europe in order to derive more powerful indicators. A refined P index could be one of the best indicators of eutrophication. Recent changes in the trophic level of surface waters could be attributed to a large extent to the change in point source P loads, i.e. to the diminishing amount of P load from municipal and industrial wastewater. The short-term improvement of water quality in the CEE countries will require further improvements in wastewater treatment, but long-term improvement will only be achieved by reducing diffuse P losses from agriculture, possibly involving changes in the land use pattern and in farming practices.
The paper describes water quality in the Raszynka River based on selected chemical parameters dependent on different land use. The research was carried out in the Raszynka River catchment, characterized by a small surface area (75.9 km2) and length (17.14 km). The river is a right tributary of the Utrata River. It is located in the Piaseczno and Pruszkow districts in the Mazowieckie voivodship. The dominant type of land use in the basin is agricultural land. Water samples were collected from 2017 to 2019 from previously designated research points at similar distances along the river. Selected physicochemical indicators examined in the samples include total alkalinity, electrolytic conductivity (EC), pH, and chemical oxygen demand (COD). Moreover, the concentration of selected substances was determined, including nitrogen compounds: NO3- (nitrates) and NH4+ (ammonium), TP (total phosphorus), and Cl- (chlorides). The results showed that the values of some of the examined indicators do not meet the standards set for first-class surface water quality. Indicators significantly exceeding the limit included ammonium, chlorides, and pH. The highest concentration of chlorides, ammonium, and nitrate was found in urbanized areas. The highest concentrations of total phosphorus and COD were determined in agricultural areas and total alkalinity in meadows.
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