Abstract:Findings of studies on the unique effects of reasoning and working memory regarding complex problem solving are inconsistent. To find out if these inconsistencies are due to a lack of symmetry between the studies, we reconsidered the findings of three published studies on this issue, which resulted in conflicting conclusions regarding the inter-relations between reasoning, working memory, and complex problem solving. This was achieved by analysing so far unpublished problem solving data from the study of Bühner, Krumm, Ziegler, and Plücken (2006) (N= 124). One of the three published studies indicated unique effects of working memory and reasoning on complex problem solving using aggregated scores, a second study found no unique contribution of working memory using only figural scores, and a third study reported a unique influence only for reasoning using only numerical scores. Our data featured an evaluation of differences across content facets and levels of aggregation of the working memory scores. Path models showed that the results of the first study could not be replicated using content aggregated scores; the results of the second study could be replicated if only figural scores were used, and the results of the third study could be obtained by using only numerical scores. For verbal content, none of the published results could be replicated. This leads to the assumption that not only symmetry is an issue when correlating non-symmetrical data, but that content also has to be taken into account when comparing different studies on the same topic.

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This work proposes a multi-method approach that combines advanced microscopy (SEM/EDX, AFM) and spectroscopy (UV-vis and FTIR) techniques. This approach not only characterises the behaviour of the additives of two commercial poly(vinyl acetate) (PVAc) and acrylic emulsion paints but also simultaneously characterises the changes in chemical composition and morphology observed in the paint films as a result of ageing due to the paints being exposed to an intense source of simulated daylight. In parallel, a series of mechanical tests were performed that correlate the chemical changes in composition and the changes observed in the films' mechanical properties. This work was a comparative study between both types of acrylic and PVAc paints. The results obtained are of great interest for the modern paint conservation field as they provide valuable information on the mid- and long-term behaviours of these synthetic paints.

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