The commonly used optical sensor based on surface plasmon-polariton wave phenomenon can sense just one chemical, because only one SPP wave can be guided by the interface of a metal and a dielectric material contained in the sensor. Multiple analytes could be detected and/or the sensing reliability for a single analyte could be enhanced, if multiple SPP-wave modes could be excited on a single metal/dielectric interface. For that to happen, the partnering dielectric material must be periodically non-homogeneous. Using a chiral sculptured thin film (CSTF) as that material in a SPP-wave platform, we show that the angular locations of multiple SPP-wave modes shift when the void regions of the CSTF are infiltrated with a fluid. The sensitivities realized in the proof-of-concept experiments are comparable to state-of-research values.
Experimentation with obliquely incident light established that all four circular reflectances of a chiral sculptured thin film backed by a metallic mirror contain strong evidence of the circular Bragg phenomenon. When the mirror is removed, strong evidence of that phenomenon is found only in the spectrum of the co-polarized and co-handed reflectance.
Multiple surface-plasmon-polariton (SPP) waves at a single free-space wavelength can be guided by the interface of a metal and a chiral sculptured thin film (STF). Multilayers comprising a chiral STF of lanthanum fluoride deposited on an aluminum thin film deposited on a glass substrate were fabricated. In some chips, a 5-nm-thick layer of silver nanoparticles was deposited at one of two selected depths in the chiral STF. The chips were then deployed in a prism-coupled configuration in a custom-built machine for surface multiplasmonic resonance imaging (SMPRI), in order to observe the effects the silver-nanoparticle layer on the multiple SPP-wave modes. The angular locations of the SPP-wave modes were found to be not greatly dependent on whether the silver-nanoparticle layer was deposited after the first or the second period of a three-periods-thick chiral STF. With aqueous solutions of sucrose as infiltrant fluids, the angular shifts of the SPP-wave modes were determined as the refractive index of the infiltrant fluid increased. The use of a charge-coupled devices (CCD) camera and upgraded motion-control equipment for SMPRI was found to increase the sensitivity of the chip. The silver-nanoparticle layer was also found to enhance the sensitivity.
Interdependence between stress, preferred orientation, and surface morphology of nanocrystalline TiN thin films deposited by dual ion beam sputtering A new technique to develop a latent sebaceous fingerprint for visualization requires the macroscopically conformal deposition of a columnar thin film on top of the fingerprint. In order to correlate the thin-film morphology to the quality of development, dense thin films as well as films comprising either upright or tilted nanocolumns were deposited on multiple samples of the same fingerprint from a donor. According to an objective grading scheme, films with upright nanocolumns provided the best development while dense films provided the worst development.
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