Mathematical models of alumina/silica gel supercritical drying with carbon dioxide were studied using supercritical drying experimental data. An alumina/silica gel with zinc chloride was synthesized and dried with superciritical carbon dioxide, and its weight change was monitored as a function of drying time. The pore size distribution of the obtained aerogel was determined using the BET method and nitrogen adsorption/ desorption. The mathematical model of the supercritical drying of the wet gel was represented as unsteady and one-dimensional diffusion of solvent through the aerogel pores filled with supercitical carbon dioxide. Parallel pore model and pores in series model were developed on the basis of the measured porous structure of the aerogel. It was found that these models which use different effective diffusivity value for each pore size were in much better agreement with the experimental data than models which use an overall effective diffusivity. The local effective diffusivity coefficients were calculated using different tortuosity values for each pore size, and they were distributed according to the pore size distribution data. Model simulations of the superciritical drying with carbon dioxide confirmed that the drying temperature and gel particle diameter have a significant influence on the drying time.
In this paper some results concerning the evolution of 3D fluid flow pattern through all four strokes in combustion chambers with entirely different bowl-in-piston geometry layouts ranging from ”omega” to “simple cylinder” were presented. All combustion chambers i.e. those with „omega“ bowls, with different profiles, and those with „cylinder“ bowls, with different squish area ranging from 44% to 62%, were with flat head, vertical valves and identical elevation of intake and exhaust ports. A bunch of results emerged by dint of multidimensional modeling of nonreactive fluid flow in arbitrary geometry with moving objects and boundaries. The fluid flow pattern during induction and compression in all cases was extremely complicated and entirely three-dimensional. It should be noted that significant differences due to geometry of the bowl were encountered only in the vicinity of TDC. Namely, in the case of “omega” bowl all three types of organized macro flows were observed while in the case of “cylinder” bowl no circumferential velocity was registered at all. On the contrary, in the case of “cylinder” bowl some interesting results concerning reverse tumble and its center of rotation shifting from exhaust valve zone to intake valve zone during induction stroke and vice-verse from intake valve zone to exhaust valve zone during compression were observed while in the case of “omega” bowl no such a displacement was legible. During expansion the fluid flow pattern is fully controlled by piston motion and during exhaust it is mainly one-dimensional, except in the close proximity of exhaust valve. For that reason it is not affected by the geometry of the bowl
In this paper some results concerning the structure and evolution of fluid flow pattern during induction and compression in 4.- valve engines with tilted valves were presented. Results were obtained by dint of multidimensional modeling of non-reactive flows in arbitrary geometry with moving boundaries. During induction fluid flow pattern was characterized with organized tumble motion followed by small but clearly legible deterioration in the vicinity of BDC. During compression the fluid flow pattern is entirely three-dimensional and fully controlled by vortex motion located in the central part of the chamber. In order to annihilate negative effects of tumble deterioration and to enhance swirling motion one of the intake valves was deactivated. Some positive and negative effects of such attempt were elucidated. The effect of turbulence model alteration in the case of excessive macro flows was tackled as well. Namely, some results obtained with eddy-viscosity model i.e. standard k-ε model were compared with results obtained with k-ξ-f model of turbulence in domain of 4.-valve engine in-cylinder flow. Some interesting results emerged rendering impetus for further quest in the near future
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