An electric small four-wheeler, categorized by the European Union as L7e so-called heavy quadricycle or microcar, is one of the solutions to eco-friendly and sustainable mobility for personal transport. Nonetheless, quadricycles typically do not offer the equivalent passive safety as larger passenger car models, in case of accidents, owing to the lack of energy absorption in the vehicle’s structure. This paper presents a proposed heavy quadricycle structure using plain weave carbon fibre-reinforced polymer in the passenger cell and aluminium alloy 6061-T6 in the crumple zone. The behaviors of electric heavy quadricycles under impact are simulated in accordance with the test guidelines of European New Car Assessment Programme using a non-linear finite element analysis via LS-DYNA to examine structural crashworthiness and characteristics. A full-frontal crash with a rigid wall at 30 km/h to 50 km/h shows that the front crush box, longerons and subframes in the crumple zone can efficiently absorb energy from a frontal crash up to 54.8%. The maximum damage in the structure occurs at the joints of the A-pillars and side beams to the front panel. Whilst the occupant safety space is safe under side collision by a 1350-kg moving deformable barrier at 50 km/h speed. However, the quadricycle tends to experience overturns from a side crash due to the vehicle’s lightweight and high center of gravity. Finally, suggestions for crashworthiness improvements to the composite passenger cell are provided based on the attained damage mechanism under a crash.