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In this study, nanocomposite poly(lactic acid) and poly(butylene adipate‐co‐terephthalate) (PLA/PBAT) blends were prepared through polymer blending in the presence of multi‐functional epoxy as a compatibilizer that could react with epoxy group and terminated end group of two phases to increase interfacial adhesion between PLA and PBAT and improve the toughness of PLA. The effects of porous clay heterostructure from mixed CTAB:CTAC surfactant in the mole ratio of 1:2 (B1C2‐PCH) were also investigated. The elongation at break of the blends reached 38%, which was eight times that of neat PLA. The cryo‐fractured surface demonstrated the interfacial adhesion caused by the interaction of the epoxy group of the reactive compatibilizer with the terminal carboxyl and hydroxyl groups of PLA and PBAT. Moreover, PBAT reduced the crystallization rate and percent crystallinity of the PLA matrix and further decreased when compatibilizer was used. Alternatively, B1C2‐PCH accelerated the heterogeneous nucleation and crystallization of the nanocomposite films. After adding small amount of B1C2‐PCH, the nanocomposite films demonstrated excellent dielectric properties. Therefore, the improvement of PLA/PBAT nanocomposite blends are capable to be further developed as polymeric capacitor films.

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