We are engaged in a systematic study of the optical and laser properties of Cr 2ϩ -doped cadmium chalcogenides. Previously, we demonstrated quasi-continuous wave lasing from Cr 2ϩ -doped Cd 0.55 Mn 0.45 Te with slope efficiencies as high as 64% and a laser tuning range from 2,170-3,010 nm. In this paper, we report the first demonstration of lasing from Cr:CdTe at room temperature. Pulsed-laser operation was obtained with a free-running spectrum centered at 2,535 nm. The slope efficiency of the laser was low (ϳ1%) because of large parasitic losses at the laser wavelength. The spectroscopic properties of Cr:CdTe are favorable for laser applications because of a large emission cross section (ϳ2.5 ϫ 10 Ϫ18 cm 2 ) and a high emission-quantum yield (ϳ88%). In addition, CdTe can easily incorporate Cr ions either through melt growth or diffusion doping. Along with our results on Cr 2ϩ :CdTe, we report on the optical properties of several other Cr 2ϩ -doped II-VI semiconductors (ZnS, ZnSe, ZnTe, CdS, CdSe, CdTe, Cd 0.9 Zn 0.1 Te, Cd 0.65 Mg 0.35 Te, Cd 0.85 Mn 0.15 Te, and Cd 0.55 Mn 0.45 Te) and compare them for applications as solid-state laser materials.
Calculation of residual stress in arteries, using the analytical approach has been quite valuable in our understanding of its critical role in vascular mechanics. Stresses are calculated at the central section of an infinitely long tube by imposing a constant axial stretch while deforming the artery from the stress-free state to its unloaded state. However, segments used to perform opening-angle measurements have finite lengths. Further, the stress-free artery configuration is assumed to be circular. Experiments show that they are slightly noncircular. The numerical approach to residual stress calculation can allow us to study both these issues. Using 3D cylindrical geometries and an isotropic material model, we investigated how segment length can affect residual stress calculations and identified the appropriate segment length for experiments. Further, we recorded and used the true noncircular stress-free state of an artery segment, computed the residual stress distribution, and compared it to that from a similar, but circular segment. Our findings suggest that segment length must be ten times the wall thickness for it to be "long" enough. We also found that the circularity assumption may be a reasonable approximation for typical arteries.
Room-temperature laser action from Cr(2+)-doped Cd(0.85)Mn(0.15)Te has been demonstrated for what is believed to be the first time. We achieved pulsed laser operation centered at ~2.5mu m by pumping into the mid-infrared absorption band of Cr(2+) ions by use of the 1.907- mum output of a H(2) Raman-shifted Nd:YAG laser. The output of the free-running Cr(2+):Cd(0.85)Mn(0.15)Te laser had a width of ~50 nm (FWHM), and the slope efficiency was calculated to be 5.5% under nonoptimum conditions.
We have for the first time demonstrated two-beam coupling energy transfer at a wavelength of 1.5 μm. Beam coupling gain coefficients of 0.6 cm−1 have been obtained in vanadium -doped CdTe with only 5 mW/cm2 incident intensity. These gain coefficients exceed typical gain coefficients in GaAs at 1.06 μm wavelength by 50%. In preliminary measurements using the moving grating technique, we have measured a gain coefficient of 2.4 cm−1. Through adjustment of the doping level, CdTe:V can be used as a sensitive photorefractive material through the 0.9–1.5 μm spectral range.
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