Solution-processable thin layer graphene is an intriguing nanomaterial with tremendous potential for electronic applications. In this work, we demonstrate that electrochemical exfoliation of graphite furnishes graphene sheets of high quality. The electrochemically exfoliated graphene (EG) contains a high yield (>80%) of one- to three-layer graphene flakes with high C/O ratio of 12.3 and low sheet resistance (4.8 kΩ/□ for a single EG sheet). Due to the solution processability of EG, a vacuum filtration method in association with dry transfer is introduced to produce large-area and highly conductive graphene films on various substrates. Moreover, we demonstrate that the patterned EG can serve as high-performance source/drain electrodes for organic field-effect transistors.

Organic electrochemical transistors (OECTs) have attracted great attention as they hold significant promise for a variety of applications ranging from printable logic circuits for electronic textiles to drivers for sensors and flat panel display pixels, as well as to artificial synapse for neuromorphic computing. [1] Because of the low working bias, high sensitivity, and stability in aqueous environments, as well as biological and mechanical compatibility with live tissues, OECTs have also recently emerged as a technological solution to a variety of diagnostic and therapeutic applications. [2] A considerable amount of work has focused, for example, on approaches exploiting the principle of OECTs for the development of biomedical tools for chemical and biological sensing, [3] electrophysiological recording, [4] monitoring of cell viability, and barrier tissue integrity, [5] to name just a few. In an OECT, the electroactive polymer constituting the channel is in direct contact with an electrolyte and with the source and drain metal electrodes ( Figure 1A). Because of the soft and permeable nature of the electroactive polymers, ions are able to penetrate into the bulk of the transistor channel. [6] The operation of an OECT relies then on a reversible ion exchange and charge compensation process, which leads to a bulk doping of the organic conducting channel and to a modulation of the electronic conductivity between the source and drain contacts. Hence, OECTs transduce a modulation in the gate voltage (V G ) to a modulation in the drain current (I D ) running through the entire bulk of the channel. The figure-of-merit that quantifies the efficiency of this transduction is the transconductance, defined as g m = ∂I D /∂V G .The current state-of-the-art active material for OECTs is the mixed ion-electron conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). The volumetric doping and dedoping of PEDOT:PSS result in a modulation of the drain-source current of several orders of magnitude with a consequent high transconductance. [7] As PEDOT:PSS is doped in its pristine state, and thus highly conducting, the OECT operates in depletion mode. In addition, several polythiophene-based polymers have been reported as efficient electroactive channel materials for enhancement mode OECTs. [8] To date, however, essentially all reported OECTs have relied on hole transport (p-type), while the development of electron Organic electrochemical transistors (OECTs) have been the subject of intense research in recent years. To date, however, most of the reported OECTs rely entirely on p-type (hole transport) operation, while electron transporting (n-type) OECTs are rare. The combination of efficient and stable p-type and n-type OECTs would allow for the development of complementary circuits, dramatically advancing the sophistication of OECT-based technologies. Poor stability in air and aqueous electrolyte media, low electron mobility, and/or a lack of electrochemical reversibility, of available high-...

Ladder-type “torsion-free” conducting polymers (e.g., polybenzimidazobenzophenanthroline (BBL)) can outperform “structurally distorted” donor–acceptor polymers (e.g., P(NDI2OD-T2)), in terms of conductivity and thermoelectric power factor. The polaron delocalization length is larger in BBL than in P(NDI2OD-T2), resulting in a higher measured polaron mobility. Structure–function relationships are drawn, setting material-design guidelines for the next generation of conducting thermoelectric polymers

Poly(3, doped with poly(styrenesulfonate) (PEDOT:PSS) has been reported as a successful functional material in a broad variety of applications. One of the most important advantages of PEDOT:PSS is its watersolubility, which enables simple and environmental friendly manufacturing processes. Unfortunately, this also implies that pristine PEDOT:PSS films are unsuitable for applications in aqueous environments. To reach stability in polar solvents, (3glycidyloxypropyl)trimethoxysilane (GOPS) is typically used to cross-link PEDOT:PSS. Although this strategy is widely used, its mechanism and effect on PEDOT:PSS performance have not been articulated yet. Here, we present a broad study that provides a better understanding of the effect of GOPS on the electrical and electronic properties of PEDOT:PSS. We show that the GOPS reacts with the sulfonic acid group of the excess PSS, causing a change in the PEDOT:PSS film morphology, while the oxidation level of PEDOT remains unaffected. This is at the origin of the observed conductivity changes.

Efficiency, current throughput, and speed of electronic devices are to a great extent dictated by charge carrier mobility. The classic approach to impart high carrier mobility to polymeric semiconductors has often relied on the assumption that extensive order and crystallinity are needed. Recently, however, this assumption has been challenged, because high mobility has been reported for semiconducting polymers that exhibit a surprisingly low degree of order. Here, we show that semiconducting polymers can be confined into weakly ordered fibers within an inert polymer matrix without affecting their charge transport properties. In these conditions, the semiconducting polymer chains are inhibited from attaining longrange order in the π-stacking or alkyl-stacking directions, as demonstrated from the absence of significant X-ray diffraction intensity corresponding to these crystallographic directions, yet still remain extended along the backbone direction and aggregate on a local length scale. As a result, the polymer films maintain high mobility even at very low concentrations. Our findings provide a simple picture that clarifies the role of local order and connectivity of domains.organic electronics | conjugated polymers | aggregation | charge transport C onjugated polymers have received significant scientific attention as the active material in devices for printed and flexible organic electronics (1, 2). Owing to their versatile chemical synthesis, inexpensive processability from solution, and unique mechanical flexibility, these materials are in fact promising for a vast array of devices in future low-cost and distributed technologies, such as integrated systems for electronic labels targeting safety, security, and surveillance applications (3). The rational design of new organic semiconductors has been guided by a thorough investigation of their limitations in charge transport, leading to the development of high-performance materials for next-generation electronic applications such as low-cost displays, solar cells, sensors, and logic circuits (4, 5). For more than a decade research has primarily focused on increasing the long-range order and the crystallinity of conjugated polymers as a strategy to improve the solid-state charge transport properties. As a result, the charge carrier mobility has increased by several orders of magnitude through the design and synthesis of highly ordered polymers. However, recent studies have suggested that the key to designing high-mobility polymers is not to increase their crystallinity but rather to improve their tolerance for disorder by allowing more efficient intra-and intermolecular charge transport pathways (6). This observation explains why mobility values obtained from recently designed seemingly disordered organic semiconductors often exceed those of polymers having a high degree of crystallinity (∼1 cm 2 ·V -1 ·s -1 ) (7-10). Indeed, polymers may exhibit little longrange order, as measured by X-ray diffraction (XRD), and yet display a remarkable degree of short-range or...