Monoelemental 2D materials such as arsenene (As) and antimonene (Sb) are creating great interest in materials research (since 2014) for designing various optoelectronic devices, energy production, and storage systems such as sensors, electrically modifiable displays, transistors, and catalysts owing to their unique properties like high surface area, optical, electrical, mechanical properties, and bio‐compatibility. Here in, an attempt has been made to write a comprehensive review on recent progress of monoelemental arsenene and antimonene focusing on tuning of properties through various techniques and their potential applications in different fields. The review is designed to explain the fundamental structures and properties in the beginning, followed by different preparation methods like exfoliation, ball milling, molecular beam epitaxy, chemical vapor deposition, and plasma‐assisted synthesis. Furthermore, the details on density functional theory studies of As an Sb and their applications in various fields such as photocatalysis, electronic and optoelectronic fields, solar cells, hydrogen evolution reaction, supercapacitors, batteries, biological applications, sensing, and electrochemical devices are reported.

Despite numerous advantages over the traditional light absorbing materials, colloidal cesium lead halide (CsPbX 3 , X = Cl, Br, or I) perovskite nanocrystals (NCs) suffer from enormous defect density, leading to shorter lifetime of charge carriers and material instability. A large number of positively and negatively charged ionic defects are inevitably formed from crystallization via high temperature. Herein, we have studied a simple post-synthesis defect passivation of blue emitting CsPbCl 3 NCs using monovalent metal ion LiCl as a dual-passivating agent. The observed effect (on optical properties) went up by leaps and bounds. Photoluminescence (PL) quantum yield increases from 2.8 to 47.6%, while PL life time increases from 0.56 to 20.79 ns. Various other chloride salts (CaCl 2 , NH 2 Cl, KCl, and NaCl) and Li salts (LiBr and LiI) with different cation and anion combinations, respectively, did not give this effect. All these together with the enhanced overall stability of NCs suggest the synergistic effect of dual passivation and deep defect passivation that leads to significant suppression of non-radiative recombination. An X-ray photoelectron spectroscopy study also reveals that this simple strategy promotes simultaneous passivation of both defects (vacancies) formed from negatively (chlorine) and positively charged ions (lead) of CsPbCl 3. Theoretical study and experimental analysis in this work, together delivers a perceptive understanding of cationic and anionic vacancy healing by LiCl in CsPbCl 3 NCs, thus enhancing its utilization as efficient blue light emitters.

Since the discovery of graphene, two dimensional (2D) materials establish a vibrant research area in energy and catalysis applications. Among all, 2D mono-elemental bismuthene have attracted researcher’s interest because of...