Ordered uniform porous carbon frameworks showing interesting morphology variations were synthesized against removable colloidal silica crystalline templates through simply altering acid catalyst sites for acid-catalyzed polymerization. These highly ordered uniform porous carbons as a catalyst supporter resulted in much improved catalytic activity for methanol oxidation in a fuel cell.
An ordered macroporous carbon with 62 nm spherical pores was synthesized using colloidal-crystal templating and found to exhibit unique gas adsorption properties that have been so far attributed to adsorption in mesopores (size below 50 nm).
Epidermal and wearable electronic sensor technologies have gained extensive interest in recent years owing to deliver real-time healthcare information to the personalized smartphone. Herein, we proposed a fully integrated wearable smart patch-based sensor system with Kirigami-inspired strain-free deformable structures having temperature and humidity sensors along with a commercial acceleration sensor. The presented fully integrated wearable sensor system easily attaches to the skin to accurately determine the body information, and integrated circuit including read-out circuit and wireless communication transfer medical information (temperature, humidity, and motion) to mobile phone to assist with emergencies due to "unpredictable" deviations and to aid in medical checkups for vulnerable patients. This article addresses the challenge of all-day continuous monitoring of human body biological signals by introducing the well-equipped breathable (water permeability ∼ 80 gm −1 •h −1), excellent adhesion to the skin (peel strength < 200 gf/12 mm), biocompatible, and conformable smart patch that can absorb the moisture (sweat) generated from the skin without any harshness and allowing the users' to continuously monitor the early detection of diagnosis. Furthermore, the proposed patchbased medical device enables wireless sensing capabilities in response to rapid variation, equipped with a customized circuit design, low-power Bluetooth module, and a signal processing integrated circuit mounted on a flexible printed circuit board. Thus, a unique platform is established for multifunctional sensors to interface with hard electronics, providing emerging opportunities in the biomedical field as well as Internet-of-Things applications.
Conformal and ultrathin coating of highly conductive PEDOT:PSS on hydrophobic uneven surfaces is essential for resistive-based pressure sensor applications. For this purpose, a water-based poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) solution was successfully exchanged to an organic solvent-based PEDOT:PSS solution without any aggregation or reduction in conductivity using the ultrafiltration method. Among various solvents, the ethanol (EtOH) solvent-exchanged PEDOT:PSS solution exhibited a contact angle of 34.67°, which is much lower than the value of 96.94° for the water-based PEDOT:PSS solution. The optimized EtOH-based PEDOT:PSS solution exhibited conformal and uniform coating, with ultrathin nanocoated films obtained on a hydrophobic pyramid polydimethylsiloxane (PDMS) surface. The fabricated pressure sensor showed high performances, such as high sensitivity (−21 kPa−1 in the low pressure regime up to 100 Pa), mechanical stability (over 10,000 cycles without any failure or cracks) and a fast response time (90 ms). Finally, the proposed pressure sensor was successfully demonstrated as a human blood pulse rate sensor and a spatial pressure sensor array for practical applications. The solvent exchange process using ultrafiltration for these applications can be utilized as a universal technique for improving the coating property (wettability) of conducting polymers as well as various other materials.
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