Bei der Photolyse des β‐Naphthylazids (I) entstehen geringe Mengen des Amins (VI) und der Azo‐Verbindung (VII), während in Gegenwart von Piperidin (II) und Tetramethyläthylendiamin (III) über Aziren‐ Zwischenstufen die beiden isomeren Diamine (IV) und (V) zu hohen Anteilen neben (VI) gebildet werden.
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