We present 10 new Spitzer detections of fullerenes in Magellanic Cloud Planetary Nebulae, including the first extragalactic detections of the C 70 molecule. These new fullerene detections together with the most recent laboratory data permit us to report an accurate determination of the C 60 and C 70 abundances in space. Also, we report evidence for the possible detection of planar C 24 in some of our fullerene sources, as indicated by the detection of very unusual emission features coincident with the strongest transitions of this molecule at ∼6.6, 9.8, and 20 μm. The infrared spectra display a complex mix of aliphatic and aromatic species such as hydrogenated amorphous carbon grains (HACs), polycyclic aromatic hydrocarbon clusters, fullerenes, and small dehydrogenated carbon clusters (possible planar C 24 ). The coexistence of such a variety of molecular species supports the idea that fullerenes are formed from the decomposition of HACs. We propose that fullerenes are formed from the destruction of HACs, possibly as a consequence of shocks driven by the fast stellar winds, which can sometimes be very strong in transition sources and young planetary nebulae (PNe). This is supported by the fact that many of our fullerene-detected PNe show altered [Ne iii]/[Ne ii] ratios suggestive of shocks as well as P-Cygni profiles in their UV lines indicative of recently enhanced mass loss.

We report high resolution spectroscopy of the moderately reddened (A V =3) early type star Cernis 52 located in a region of the Perseus molecular cloud complex with anomalous microwave emission. In addition to the presence of the most common diffuse interstellar bands (DIBs) we detect two new interstellar or circumstellar bands coincident to within 0.01% in wavelength with the two strongest bands of the naphthalene cation (C 10 H + 8 ) as measured in gas-phase laboratory spectroscopy at low temperatures and find marginal evidence for the third strongest band. Assuming these features are caused by the naphthalene cation, from the measured intensity and available oscillator strengths we find that 0.008 % of the carbon in the cloud could be in the form of this molecule. We expect hydrogen additions to cause hydronaphthalene cations to be abundant in the cloud and to contribute via electric dipole radiation to the anomalous microwave emission. The identification of new interstellar features consistent with transitions of the simplest polycyclic aromatic hydrocarbon adds support to the hypothesis that this type of molecules are the carriers of both diffuse interstellar bands and anomalous microwave emission.

The detection of C 60 and C 70 fullerenes in young planetary nebulae and in reflection nebulae suggests that these molecules are more common in certain astrophysical environments than previously thought. The dependence on temperature of the positions and widths of the infrared bands of the C 60 and C 70 fullerenes is needed for a firm qualitative detection of these molecules in space. Furthermore, the integrated molar absorptivity (in km mol −1 ) of each infrared absorption band is required for a quantitative determination of the abundance of C 60 and C 70 in space. In this paper, we report on the temperature dependence of the wavelength shift and integrated molar absorptivity of the infrared bands of the C 60 and C 70 fullerenes. The measurements have been made in a KBr matrix in the temperature range between −180 • C and +250 • C. The experimental data have been extrapolated to derive both the infrared band shift and the integrated molar absorptivity of the C 60 and C 70 fullerenes at absolute zero temperature.

We show that photoabsorption by fullerenes and buckyonions (multishell fullerenes) explain the shape, width, and peak energy of the most prominent feature of interstellar absorption, the UV bump at 2175 . The predicted A optical and near-infrared transitions for these molecules also offer a potential explanation for the long-standing problem of the identity of the diffuse interstellar bands. The implied ubiquitous distribution of fullerenes may also account for the anomalous galactic microwave emission detected by cosmic microwave background experiments. Comparing theoretical cross sections and astronomical data, we estimate a density of fullerenes in the diffuse interstellar medium of 0.1-0.2 parts per million, consistent with the findings in meteorites. Fullerenebased molecules appear to be a major carbon reservoir in the interstellar medium.