Polymer blends are generally categorized into two main classes: miscible blends that exist in a single homogeneous phase exhibiting synergistic properties and immiscible blends that have 2 or more different phases. There is also a third category of blends called technologically compatible blend, which exist in two or more different phases on micro scale, yet displays combination of properties. Ethylene-propylene-diene rubber (EPDM) and Hexa fluoropropylene-vinylidinefluoride dipolymer, Fluoroelastomer (FKM) blends with and without compatibilizer (MA-g-EPDM) were prepared by two-roll mill mixing. The aim of the work is to find out the best blend ratio and the amount of compatibilizer loading on thermal and mechanical properties by applying a novel mathematical programming technique called Data Envelopment Analysis (DEA). Using the different concentration of the ingredients used as inputs and the extent to which certain properties satisfied by the blends as outputs, a DEA model is developed. The blends which will be referred to as Decision Making Units (DMUs) were classified in terms of their efficiency. It is observed that the efficiency of all the compatibilized blends is higher than that of uncompatibilized blends. The maximum efficiency is obtained for 2.5 phr compatiblized blend.
Data envelopment analysis is a widely used non-parametric technique to measure and evaluate the relative efficiency of similar decision making units. Classical DEA models evaluate the efficiency from input and output values which are precise or crisp in nature.But when it is applied in real life situations input and output values vary even over small intervals of time. Hence mostly the data will be imprecise or fluctuating, which can very well be modelled by fuzzy set theory. So in this paper a DEA model is developed which can handle input output values which are fuzzy in nature. The fuzzy DEA model is developed as a fully fuzzy fractional programming problem and a methodology is suggested for solving it.
The paper describes a method to solve an ILP by describing whether an approximated integer solution to the RLP is an optimal solution to the ILP. If the approximated solution fails to satisfy the optimality condition, then a search will be conducted on the optimal hyperplane to obtain an optimal integer solution using a modified form of Branch and Bound Algorithm.
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