Reaction of Bl0HI4 with Et3PAuMe affords the triple cluster [(H12BloA~)(A~PEt3)4(AuBloH12)], and with Cy3PAuMe (CY = cyclohexyl) the substituted complex [Cy3PAu(Bl0Hl3)] is isolated; a mechanism for the formation of the triple cluster is proposed.
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