The synthesis of pyrroles via acceptorless dehydrogenative condensation of secondary alcohols and 1,2-amino alcohols mediated by a robust and reusable catalyst based on nanometer-sized iridium particles †

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Transition metal oxides show fascinating physical properties such as high temperature superconductivity, ferro‐ and antiferromagnetism, ferroelectricity or even multiferroicity. The enormous progress in oxide thin film technology allows us to integrate these materials with semiconducting, normal conducting, dielectric, or non‐linear optical oxides in complex oxide heterostructures, providing the basis for novel multi‐functional materials and various device applications. Here, we report on the combination of ferromagnetic, semiconducting, metallic, and dielectric materials properties in thin films and artificial heterostructures using laser molecular beam epitaxy. We discuss the fabrication and characterization of oxide‐based ferromagnetic tunnel junctions, transition metal‐doped semiconductors, intrinsic multiferroics, and artificial ferroelectric/ferromagnetic heterostructures – the latter allow for the detailed study of strain effects, forming the basis of spin‐mechanics. For characterization we use X‐ray diffraction, SQUID magnetometry, magnetotransport measurements, and advanced methods of transmission electron microscopy (TEM) with the goal to correlate macroscopic physical properties with the microstructure of the thin films and heterostructures. The combination of magnetic properties with dielectric, semiconducting, or ferroelectric materials in one and the same material (e.g. magnetic semiconductors (MS) or intrinsic multiferroics) as well as in artificial heterostructures (e.g. ferromagnetic/dielectric heterostructures for magnetic tunnel junctions (MTJs) or artificial multiferroic heterostructures) allows for the design of materials with novel functionalities and provides the basis for various device applications.

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The aim of the joint industrial and academic project "SupraMetall" is to enable the large scale production of superconducting tapes. This is a report of the recent achievements in the production of cube textured metal substrates and the coating techniques of the buffer and superconductive layers. The final coated conductor tapes of 2 m length reached critical current densities of 120 A/cm-width.