The analysis of data of the ground-level ozone concentration and accumulated ozone exposure over a threshold of 40 ppb (AOT40) in the rural areas of Lithuania is presented. Trends in the annual ozone mean, 95th and 25th percentiles were determined as statistically not significant at Preila and Rugsteliskes sites during the 1994-2004 period. Trends in the ozone concentration and its percentiles in the air masses arriving to Preila station in "polluted" and "unpolluted" sectors have been examined. Statistically significant changes in the ozone annual mean and 25th percentile were found in air masses in both "polluted" and "unpolluted" sectors in the 1988-2002 period. The trend analysis in the ozone monthly mean and percentiles for each month of the year revealed the main changes in the ozone level in both sectors during January-May. Insignificant downward trends in monthly 95th percentile in "unpolluted" sector and upward trends in "polluted" sector were found during summer months. Values of AOT40 for the protection of forests as well as crops and semi-natural vegetation were determined during the 1994-2004 period. The estimated AOT40 values for the protection of forests were lower than the critical level at Lithuanian rural sites but AOT40 values for the protection of crops and semi-natural vegetation were found to be higher than the critical level at both sites.

Continuous ozone concentration measurements at rural sites in Lithuania have been performed since 1982. Long-term ozone data show an increasing trend 0.4 ppb y(-1) in annual mean concentrations during the period 1982-2008, although ozone peak values show an insignificant tendency to decrease. Several studies were performed to evaluate the ozone effect on the main plant species of Lithuanian forests. A strong positive correlation was found between values for the accumulated doses over a threshold of 40 ppb index and the defoliation of Fraxinus excelsior trees in Lithuanian forests during 1991-2008. A strong correlation was found between ozone exposure and the proportion of healthy F. excelsior, Betula sp., and Alnus incana, trees indicating that in Lithuania the deciduous species are more sensitive to ozone than conifers and that healthier trees may be better indicators of the changing environment. The results of the studies suggest that the observed levels of ozone are sufficiently high to have negative effects on the vegetation in Lithuania.

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