Observations of a shock wave propagating through a decaying plasma in the afterglow of an impulse high-voltage nanosecond discharge and of a surface dielectric barrier discharge in the nanosecond range were analysed to determine the electron power transferred into heat in air plasmas in high electric fields. It was shown that approximately half of the discharge power can go to heat for a short (∼1 µs at atmospheric pressure) period of time when reduced electric fields are present at approximately 103 Td. A kinetic model was developed to describe the processes that contribute towards the fast transfer of electron energy into thermal energy under the conditions considered. This model takes into account previously suggested mechanisms to describe observations of fast heating in moderate (∼102 Td) reduced electric fields and also considers the processes that become important in the presence of high electric fields. Calculations based on the developed model agree qualitatively with analyses of high-voltage nanosecond discharge observations.

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International audienceThe ignition dynamics of a CH4: O2: N2: Ar = 1: 4: 15: 80 mixture by a high-voltage nanosecond discharge is simulated numerically with allowance for experimental data on the dynamics of the discharge current and discharge electric field. The calculated induction time agrees well with experimental data. It is shown that active particles produced in the discharge at a relatively low deposited energy can reduce the induction time by two orders of magnitude. Comparison of simulation results for mixtures with and without nitrogen shows that addition of nitrogen to the mixture leads to a decrease in the average electron energy in the discharge and gives rise to new mechanisms for accumulation of oxygen atoms due to the excitation of nitrogen electronic states and their subsequent quenching in collisions with oxygen molecules. Acceleration of the discharge-initiated ignition is caused by a faster initiation of chain reactions due to the production of active particles, first of all oxygen atoms, in the discharge