Thermal aging of natural ester oil shows drastic reduction in partial discharge inception voltage (PDIV) and a significant variation is observed only above a certain aging time, under AC, DC, high frequency AC voltages and with harmonic voltages with different total harmonic distortion. Weibull distribution studies on PDIV measurements indicate a reduction in scale parameter (α) with increase in thermal aging temperature. A characteristic reduction in breakdown voltage was observed with the thermally aged ester oil, under AC, DC and standard lightning impulse voltage. The breakdown voltage variation with aged ester oil follows normal distribution. Ultraviolet (UV) analysis of ester oil thermally aged at 160°C has revealed a regular shift of the derived absorbance parameter to longer wavelengths. The interfacial tension and turbidity exhibits an inverse relationship with the thermally aged ester oil. Gas chromatography/mass spectrometric analysis of the thermally aged ester oil predicted the formation of more carboxylic acids and ketones with aging duration. The steady-state fluorescence on thermally aged ester oil exhibits a shift in its emission profile, which is in tandem with the UV absorption spectroscopic analysis. Fluorescence analysis can be adopted as a real-time monitoring tool in transformers, to understand the condition of liquid insulation. The viscosity dependence on the wavelength of derivative absorption maxima follows a direct relationship with the thermally aged natural ester oil.

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Phosphor materials with broad spectral range and an average emission lifetime (20 μs) have been achieved from carbon dots (CDs)À NaCl crystals. A one-pot synthesis pathway has been developed for CDsÀ NaCl crystals formation at room temperature. Precursor for CDs materials was screened at room temperature by oxidation methodology from different simple sugar molecules. CDs (size less than 10 nm) prepared from the fructose sugar exhibit most intense emission. Utilizing ripe banana peel (contains~27% of fructose) as a precursor for the carbon dot formation, whitelight emission with a CIE index of (0.29, 0.34) has been achieved from the single source with CDsÀ NaCl crystals upon excitation at 430 nm. The crystals also function as Fabry-Perot (FÀ P) mode resonator for lasing, with a laser threshold value of 0.9 mW and a resonating Q-factor of 207. These results outline a new approach for realizing FÀ P lasing and white light emission from a non-toxic green source with a quick, facile and low-cost synthesis procedure.

Fecal matter is considered to be one of the primary sources of water pollution. Understanding the aggregation behavior of the fecal pigments (FPs) could play a critical role in their detection and analysis. This work shows that in aqueous media, the fluorescence of FPs indicates the presence of multiple emitting species, which have been assigned to monomers, lower-order Haggregates (dimers), and higher-order H-aggregates. Steady-state absorbance, fluorescence and time-resolved fluorescence decay studies conclude that the emission of FPs in aqueous medium indicates H-type of aggregation, even up to nanomolar and subnanomolar concentrations. Four sets of independent experiments involving the variation of (i) concentration of FPs, (ii) temperature, (iii) pH, and (iv) ethanol/water composition as solvent media suggest the presence of monomer (540 nm), dimer (516 nm), and higher-order aggregates (500 nm) of FPs in aqueous solutions. The dimeric FP species appear to be present in the entire concentration range of 1 pM to 1 μM. Fluorescence lifetimes of H-aggregates are relatively longer as compared to the corresponding monomers. Hydrogen bonding appears to play an important role in forming H-aggregates in the aqueous phase of FPs as observed in the IR spectra of the FPs in dichloromethane. Density functional theory (DFT) calculations using the B3LYP functional and the LANL2DZ basis set show the contributions of π−π stacking and hydrogen-bonding interactions toward the formation of H-aggregated dimer of FPs in aqueous media.

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