Waste tires have been identified as one of the contributors to environmental problems and the issue of inadequate landfill spaces. The lack of consistent and systematic approaches such as specific regulations/laws or mechanisms of waste management to waste tires, limited application of technology for recycling waste tires and lack of awareness on the impacts of waste tires problem, make waste tires a source of environmental pollution. Various researches have been conducted on recycling waste tires into polymer bends, and materials to harden concretes, fuels and adsorbent. Researchers suggested that pyrolysis is the current trend of recycling waste tire to harvest the saleable pyrolysis oil and the recycled carbon black. Therefore, this review attempts to compile relevant knowledge about the potential of adsorbent derived from waste tires to be applied in the removal of various types of pollutants like heavy metals, organic pollutants, dye and air/gaseous pollutant. Studies were carried out on revealing the properties and the characteristics of activated carbon derived from waste tire as effective adsorbent which influence the application performance at liquid or gas phase. In addition, the challenges in the production of activated carbon derived from waste tire were discussed.
Biomass exists in two forms, woody and non woody. The woody biomass originates from plants while non-woody form originates from excess waste of animals, industry and crops. Biomass feedstock can be used in the form of liquid fuels, heat, electric power, and bio-based products. Fig. 1 shows most common biomass feedstock [2]. ABSTRACTIn this paper the authors provide comparative evaluation of current research that used liquefaction and pyrolysis method for bio-oil production from various types of biomass. This paper review the resources of biomass, composition of biomass, properties of bio-oil from various biomass and also the utilizations of bio-oil in industry. The primary objective of this review article is to gather all recent data about production of bio-oil by using liquefaction and pyrolysis method and their yield and properties from different types of biomass from previous research. Shortage of fossil fuels as well as environmental concern has encouraged governments to focus on renewable energy resources. Biomass is regarded as an alternative to replace fossil fuels. There are several thermo-chemical conversion processes used to transform biomass into useful products, however in this review article the focus has been made on liquefaction and pyrolysis method because the liquid obtained which is known as bio-oil is the main interest in this review article. Bio-oil contains hundreds of chemical compound mainly phenol groups which make it suitable to be used as a replacement for fossil fuels.
Lignocellulosic biomass especially, sugarcane bagasse Saccharum barberi sp., appears to be a more suitable material for partial substitution of transport fuel (diesel) than Saccharum officinarum sp., due to its structural similarity to transport fuel (diesel). Besides that, less research has been implemented on this type of species. Bio-oil can be implemented as biodiesel by processing it further using chemical reactions such as hydrodeoxygenation and cracking with zeolite catalyst. Hence, the purpose of this study is to determine the compatibility of pyrolytic bio-oil produced from Saccharum barberi sp. in comparison with S. officinarum sp. for use as transport fuel (diesel) in automotive applications. This purpose can be accomplished by comparing the oil’s bio-physiochemical properties for both species. The experiment is conducted on a bench-scale on which bio-oil of Saccharum barberi sp. is secured from the catalytic pyrolysis process at a temperature of 500°C and heating rate of 50°C/min with the addition of ZSM-Zeolite catalyst. Thermogravimetric analysis of Saccharum barberi sp. reveals that cellulose is more reactive than lignin, evidenced by the high percentage of weight loss at temperatures ranging from 251°C to 390°C. The high contents of carbon (40.7%) and hydrogen (6.50%), as well as slight traces of sulphur (0.08%) and nitrogen (0.85%), in bio-oil (Saccharum barberi sp.) indicate that it is conceivable to be partially used for replacement in biofuel production. Overall physiochemical properties reveal that Saccharum barberi sp. shows more potential than S. officinarum sp. Gas chromatography–mass spectrometry analysis reveals that bio-oil consists of high amounts of aromatic hydrocarbon (26.2%), phenol (14.8%) and furfural (13.0%) in comparison to S. officinarum sp. Biofuel was produced from sugarcane bagasse (Saccharum barberi sp.) in a bench-scale pyrolysis reactor at 500°C using a zeolite catalyst. Measured properties of the biofuel make it suitable for partial substitution of diesel in transport fuel.
Bioactive secondary metabolites derived from herbs are examined for their suitability of conversion into nanoforms having flexible morphological controls, surface stabilizations and surface functionalization. This can lead to stable chemical conjugations based on molecular recognition for their possible applications in the form of smart pharmaceuticals, nutraceuticals, cosmaceuticals and many other related areas of human healthcare using green chemistry routes. Using the principles of nanoscience and technology in association with genomics and proteomics, an attempt has been made to decipher whether a suitable form of drug discovery and targeted drug delivery like schemes are feasible in case of such nano phytochemicals using various kinds of nanosize carriers and labelling molecules already identified in the course of investigations of contemporary single molecule drug developments. Additional efforts can clarify whether such species will be successful in the early detection of diseases based on marker molecules. Once identified, these green phytochemicals will certainly replace many hazardous chemical compounds by their environmentally friendly and sustainable forms in times to come.
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