Scandium (Sc) is used in several modern industrial applications. Recently, significant Sc concentrations (~100 ppm) were reported in some nickel-cobalt lateritic ores, where Sc may be valuably co-produced. However, Sc is typically not included in routine analyses of Ni-Co ores. This contribution examines the relevance of using routinely analysed elements as geochemical proxies for estimating Sc concentration and distribution. Three Ni-Co lateritic deposits from New Caledonia were investigated. In each deposit, Sc is well correlated with Al2O3. The slopes of deposit-scale Sc-Al2O3 regression lines are remarkably controlled by the composition of enstatite from the parent peridotite. In all deposits, maximum Sc enrichment occurs in the yellow limonite, above the highest Ni and Co enrichment zones. Sc- and Al-bearing crystalline goethite is predominant in the oxide-rich zones, though Sc shows a higher affinity for amorphous iron oxides than Al. We propose that, in already assayed Ni-Co lateritic ores, the concentration and distribution of Sc can be estimated from that of Al. Deposit-scale Sc-Al2O3 correlations may be determined after analysing a limited number of spatially and chemically representative samples. Therefore, mining operators may get a first-order evaluation of the Sc potential resource in Ni-Co lateritic deposits at low additional costs.

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Silicification in New Caledonian pseudo-karsts developed on peridotite was assessed using δ18O and δ30Si pairs on quartz cements. The objective was to document the chronology of pseudo-karst development and cementation relative to geomorphic evolution. The latter began at the end of the Eocene with the supergene alteration of peridotites and the subsequent formation of extended lateritic weathering profiles. Neogene uplift favoured the dismantling of these early lateritic profiles and valley deepening. The river incision resulted in (i) the stepping of a series of lateritic paleo-landforms and (ii) the development of a pseudo-karst system with subvertical dissolution pipes preferentially along pre-existing serpentine faults. The local collapse of the pipes formed breccias, which were then cemented by white quartz and Ni-rich talc-like (pimelite). The δ30Si of quartz, ranging between −5‰ and −7‰, are typical of silcretes and close to the minimum values recorded worldwide. The estimated δ18O of −6 to −12‰ for the fluids are lower than those of tropical rainfall typical of present-day and Eocene–Oligocene climates. Evaporation during drier climatic episodes is the main driving force for quartz and pimelite precipitation. The silicification presents similarities with silcretes from Australia, which are considered predominantly middle Miocene in age.

<p>Laterite nickel-ore formation in New Caledonia is classically assumed to be governed by supergene processes, and downward migration of waters with Ni-enrichment at the basis of the laterite profile. However, Ni-ore distribution's heterogeneity seems to have been favoured by secondary processes controlled by the combined effects of inherited tectonics, geomorphological evolution and hydrologic systems since the primary laterite formation. Fluid flow and mass transfer processes are not purely downward at low-temperature conditions, but can also be related to lateral fluid circulations, and local drainage along damaged zones in the vicinity of faults (Cathelineau et al., 2016a; 2016b; Myagkiy et al., 2019). This study aims to investigate through reactive transport modelling the impact of discrete fracture on the Ni distribution.</p><p><br>We simulate the dissolution of olivine profile where fractures are the main channels of the fluid-flow. Olivine dissolution is assumed to be kinetically controlled whereas the precipitation of secondary weathering products is considered to occur according to local equilibrium. Results from two different numerical approaches are presented and discussed. The first one is based on a 1D dual-porosity model of a vertically oriented column of serpentinized olivine using PhreeqC associated with the llnl.dat thermodynamic database. The second one is a 2D modelling of hydro-chemical processes in fractured porous media based on the coupling of PhreeqC and Comsol Multiphysics through ICP. While the 1D model aims to describe the general trend of the progression of the weathering front and the global mineral redistribution, the 2D model focuses on particular fracture geometry and hotspot moments of the dissolution process to highlight crucial transition and redistribution of the different mineral phases in relation with the spatial distribution of fractures.</p><p><br>In the 1D dual-porosity model, the fractures are modelled as advective cells connected to a diffusive cell containing the main part of olivine. Two different geochemical models are thus designed. The first one describes the fracture and the advective area's geochemical behaviour, while the second one focuses on the matrix in the diffusive area. The 2D model extends the work initiated by Myagkiy et al. (2019) on simple configurations. The fractures are modelled herein as 1D discrete surfaces interacting with a porous matrix of olivine. Different fracture configurations are studied to assess their impact on mineral redistribution.</p><p><br>Results from both modellings are then compared with observed field data from New Caledonia and previous modelling of an olivine profile without fractures (Myagkiy et al., 2017) to validate the models and highlight the differences induced by the fracture network.</p>

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