Influences of process conditions on microstructure and dielectric properties of ceramic-polymer composites are systematically studied using CaCu3Ti4O12 (CCTO) as filler and P(VDF-TrFE) 55/45 mol.% copolymer as the matrix by combining solution-cast and hot-pressing processes. It is found that the dielectric constant of the composites can be significantly enhanced–up to about 10 times – by using proper processing conditions. The dielectric constant of the composites can reach more than 1,000 over a wide temperature range with a low loss (tan δ ~ 10−1). It is concluded that besides the dense structure of composites, the uniform distribution of the CCTO particles in the matrix plays a key role on the dielectric enhancement. Due to the influence of the CCTO on the microstructure of the polymer matrix, the composites exhibit a weaker temperature dependence of the dielectric constant than the polymer matrix. Based on the results, it is also found that the loss of the composites at low temperatures, including room temperature, is determined by the real dielectric relaxation processes including the relaxation process induced by the mixing.

Purpose Human space exploration to date has been limited to low Earth orbit and the moon. The International Space Station (ISS) provides a unique opportunity for researchers to prove out the technologies that will enable humans to safely live and work in space for longer periods and venture farther into the solar system. The ability to manufacture parts in-space rather than launch them from earth represents a fundamental shift in the current risk and logistics paradigm for human space exploration. The purpose of this mission is to prove out the fused deposition modeling (FDM) process in the microgravity environment, evaluate microgravity effects on the materials manufactured, and provide the first demonstration of on-demand manufacturing for space exploration. Design/methodology/approach In 2014, NASA, in cooperation with Made in Space, Inc., launched a 3D printer to the ISS with the goal of evaluating the effect of microgravity on the fused deposition modeling (FDM) process and prove out the technology for use on long duration, long endurance missions where it could leveraged to reduce logistics requirements and enhance crew safety by enabling a rapid response capability. This paper presents the results of testing of the first phase of prints from the technology demonstration mission, where 21 parts where printed on orbit and compared against analogous specimens produced using the printer prior to its launch to ISS. Findings Mechanical properties, dimensional variations, structural differences and chemical composition for ground and flight specimens are reported. Hypotheses to explain differences observed in ground and flight prints are also developed. Phase II print operations, which took place in June and July of 2016, and ground-based studies using a printer identical to the hardware on ISS, will serve to answer remaining questions about the phase I data set. Based on Phase I analyses, operating the FDM process in microgravity has no substantive effect on the material produced. Practical implications Demonstrates that there is no discernable, engineering significant effect on operation of FDM in microgravity. Implication is that material characterization activities for this application can be ground-based. Originality/value Summary of results of testing of parts from the first operation of 3D printing in a microgravity environment.

No abstract

Influence of the coupling agent on microstructure and dielectric properties of ceramic–polymer composites is systematically studied using CaCu3Ti4O[Formula: see text] (CCTO) as the filler, trichloro-(1H,1H,2H,2H-perfluorooctyl)-silane (Cl3-silane) as coupling agent, and P(VDF-CTFE) 88/12[Formula: see text]mol.% copolymer as the matrix. It is demonstrated that Cl3-silane molecules can be attached onto CCTO surface using a simple process. The experimental results show that coating CCTO with Cl3-silane can improve the microstructure uniformity of the composites due to the good wettability between Cl3-silane and P(VDF-CTFE), which also significantly improves the electric breakdown field of the composites. It is found that the composites using CCTO coated with 1.0[Formula: see text]wt.% Cl3-silane exhibit a higher dielectric constant with a higher electric breakdown field. For the composites with 15[Formula: see text]vol.% CCTO that is coated with 1.0[Formula: see text]wt.% Cl3-silane, an electric breakdown field of more than 240[Formula: see text]MV/m is obtained with an energy density of more than 4.5[Formula: see text]J/cm3. It is also experimentally found that the dielectric constant can be used to easily identify the optimized content of coupling agent.

Various physical treatments of BaCuO 2 samples result in irreversible changes in its Raman spectrum. The prominent peaks at 576 and 628 cm −1 in the spectra of sintered pellets of BaCuO 2 disappear upon further annealing in air or oxygen or upon mere regrinding of the pellets. Further annealing in air, oxygen, or vacuum does not restore these peaks. Similar but less intense peaks reappear upon exposure of pellets to laboratory environment for several weeks, but these broaden and disappear upon further exposure. These spectral characteristics contrast with those observed in Y123 Raman spectrum. It is concluded that the peaks at 582 cm −1 and 636 cm −1 in the spectra of sintered pellets of Y123 are not due to the presence of BaCuO 2.