The propagation of roughness from a patterned silicon surface by
polymer thin films was
measured as a function of film thickness, time, and surface interaction
using atomic force microscopy
and synchrotron X-ray reflection. In the presence of an
interacting surface, the decay length of the surface
modulation was much longer than that observed in simple liquids.
By measuring the time dependence
of the surface corrugation amplitude, we were able to extract a surface
diffusion coefficient by applying
a modified version of the Mullins theory for surface diffusion in
crystalline solids. The measured diffusion
coefficients were an order of magnitude smaller than in the bulk, and
scaled as 1/M
3/2, in agreement
with
previous SIMS results. The results are interpreted in terms of
surface interactions confining polymer
chains over distances larger than the radii of gyration.
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