The thermal conductivity of heterogeneous materials used in thermal batteries is difficult to measure. These materials must be handled under controlled atmosphere with methods adapted to their porous nature. The method presented in this work uses heating plates to send a sinusoidal thermal signal to the tested sample. The whole setup is confined in a glovebox to ensure the composition and hygrometry of the atmosphere. Parametric computer simulations with varying thermal conductivity (λ) of the sample and thermal resistance (h) of the contacts as inputs were performed to calculate the phase shifts associated with two thicknesses of the sample. Experimental measurements of phase shifts on these two configurations allowed the identification of the only couple (λ, h) which matches the phase shifts on the respective thicknesses. This method is validated using the reference material BK7 at different temperatures. Thermal conductivities of different materials used in thermal batteries are also given using this method.

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The thermal conductivity of heterogeneous materials used in thermal batteries is difficult to measure. These materials must be handled under controlled atmosphere with methods adapted to their porous nature. The method presented in this work uses heating plates to send a sinusoidal thermal signal to the tested sample. The whole setup is confined in a glovebox to ensure the composition and hygrometry of the atmosphere. Parametric computer simulations with varying thermal conductivity (λ) of the sample and thermal resistance (h) of the contacts as inputs were performed to calculate the phase shifts associated with two thicknesses of the sample. Experimental measurements of phase shifts on these two configurations allowed the identification of the only couple (λ,h) which matches the phase shifts on the respective thicknesses. This method is validated using the reference material BK7 at different temperatures. Thermal conductivities of a heterogeneous cathode used in thermal batteries is also given using this method.