The renewable biomass material obtained from rice husk, a low-cost agricultural waste, was used as a precursor to synthesize a highly porous graphene-based carbon as electrode material for supercapacitors. Activated graphene-based carbon (AGC) was obtained by a two-step chemical procedure and exhibited a very high specific surface area (SSA) of 3292 m2 g−1. The surface morphology of the synthesized materials was studied using scanning and transmission electron microscopy (SEM, TEM). Furthermore, the AGC was modified with nickel hydroxide Ni(OH)2 through a simple chemical precipitation method. It was found that the most significant increase in capacitance could be reached with Ni(OH)2 loadings of around 9 wt.%. The measured specific capacitance of the pure AGC supercapacitor electrodes was 236 F g−1, whereas electrodes from the material modified with 9 wt.% Ni(OH)2 showed a specific capacitance of up to 300 F g−1 at a current density of 50 mA g−1. The increase in specific capacitance achieved due to chemical modification was, therefore 27%.
The scales of porous carbon materials usage are constrained by their considerably high cost. Therefore, development of new methods for production of porous carbon with the necessary complex of properties from cheap raw materials is actual. Also, porous carbon materials can be used for growth of carbon nanotubes as a matrices of catalyst particles. Herein, the method of fabrication porous carbon materials from waste of oil industry and their use as a matrices of catalyst particles to growth of CNT was developed. CNTs was synthesized by CVD using as hydrocarbon source - propan-butane gas mixture, as catalyst - Ni particles at 650°C, 700°C, 750°C, 800°C. Obtained carbon materials was investigated by Raman spectroscopy and by scanning electron microscope. Investigations on the properties of the obtained porous materials show soot particles sedimented in pores reduce well nanoparticles of metals from salts which act as nuclei for the growth of multiwall carbon nanotubes during pyrolysis of hydrocarbons by CVD method.
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