A combined treatment of electrocoagulation and ultrasound was proposed to solve some problems which exist in the phosphorus removal processes in fine chemical industry. The intermittently discharged wastewater has the features of high initial phosphorus concentration and wide initial pH variation. The electrocoagulation-ultrasound effective performance for the removal of phosphorus was investigated. The results obtained from synthetic wastewater showed that the total phosphorus (TP) decreased from 86 to about 0.4 mg/L, and the removal efficiency reached about 99.6 %, when ultrasound was applied to the electrocoagulation cell under the optimum working conditions in 10 min. Comparatively, the TP removal efficiency of electrocoagulation group was 81.3 % and the ultrasound group has almost no change. Therefore, we can conclude that the electrocoagulation and ultrasound synergistic effect can effectively degrade high-phosphorus wastewater. We have discussed the impact of various parameters on the electrocoagulation-ultrasound based on the phosphorus removal efficiency. The results obtained from synthetic wastewater showed that the optimum working pH was found to be 6, allowing the effluent to be met the emission standards without pH adjustment. An increased current enhanced the speed of treatment significance, but higher current (>40 mA/cm(2)) enhanced ultrasonic cavitation effect causing flocculation ineffective. In addition, it was found that the optimum ultrasonic power was 4 W/cm(2) and the frequency was 20 kHz. The best ultrasound intervention and ultrasonic irradiation time were processed with electrocoagulation simultaneously. The results indicated that the electrocoagulation-ultrasound could be utilized as an attractive technique for removal of phosphate in the real wastewater.
This study demonstrated that a phase transformation of HA into α-TCP and CaO was achieved by sintering. The cell tests indicated that the CPB has favorable in vitro cellular performance, which implied that it presented potential as bone substitute.
Recently, Ti–Ta alloys have been expected to be as candidates for dental or orthopedic implants because of their low elastic modulus and high corrosion resistance. However, Ti–Ta alloys do not have the properties to protect against bacterial infection. An anti-bacterial coating was fabricated on the Ti-Ta alloy surface by anodic oxidation (AO) and its surface properties were investigated. The anodic oxidized (AOed) film exhibited a roughened surface dotted with micropores. In addition, the AOed surface is more hydrophilic than the Ti-Ta alloy. The results of an anti-bacterial test revealed that the AOed surface possessed excellent anti-bacterial rate against Staphylococcus aureus (98.5%).
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