Tropical clay soil was compacted at different moisture conditions (dry, wet and optimum) and compactive efforts (Reduced proctor, Standard proctor, West African standard and Modified proctor). Experimental Soil-Water Characteristics (SWC) of the soil was derived using the pressure plate extractor equipment and SWC Curves (SWCC) plotted as gravimetric water content versus logarithm of matric suction. The Air Entry Values (A.E.V) obtained from experimental work ranged from 21 kPa to 59 kPa and compared favourably well with those estimated from predictive models with values of 23 kPa to 52 kPa. Specimens compacted with greater compactive effort (Modified proctor) and at optimum moisture content produced the largest air entry value of 59 kPa and reduced air voids. Changes observed in the shape of the SWCC were consistent with changes in pore size which occurred by varying compaction conditions. The shape of the soil-water characteristics curve was found to depend on the soil structure, compactive water content and compactive effort and not solely on the percentage of fine particles.

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Soils containing inorganic compounds are frequently encountered by transportation agencies during construction within the right-of-way, and they pose a threat to human health and the environment. As a result, construction activities may experience project delays and increased costs associated with management of inorganic compounds containing soils required to meet environmental regulations. Recalcitrance of metal-contaminated soils toward conventional treatment technologies is exacerbated in clay or organic content-rich fine-grained soils with low permeability and high sorption capacity because of increased treatment complexity, cost, and duration. The objective of this study was to develop an accelerated in situ electrochemical treatment approach to extract inorganic compounds from fine-grained soils, with the treatment time comparable to excavation and off-site disposal. Three reactor experiments were conducted on samples collected from two borehole locations from a field site in Illinois that contained arsenic (As)(~7.4 mg/kg) and manganese (Mn)(~700 mg/kg). A combination of hydrogen peroxide (H2O2) and/or citrate buffer solution was used to treat the soils. A low-intensity electrical field was applied to soil samples using a bench-scale reactor that resembles field-scale in situ electrochemical systems. For the treatment using 10% H2O2 and citrate buffer solution, average removal of 23% and 8% were achieved for Mn and As, respectively. With 4% H2O2 and citrate buffer, 39% and 24% removal were achieved for Mn and As; while using only citrate buffer as the electrolyte, 49% and 9% removal were achieved for Mn and As, respectively. All chemical regimes adopted in this study reduced the inorganic compound concentrations to below the maximum allowable concentration for Illinois as specified by the Illinois Environmental Protection Agency. The results from this work indicate that electrochemical systems that leverage low concentrations of hydrogen peroxide and citrate buffer can be effective for remediating soils containing manganese and arsenic.