X-Ray crystal structure analyses reveal that the title complexes have a 3-D network, in which N(CN)2− and pyrimidine contribute µ-1,5-bridged 2-D and µ-1,3-bridged 1-D structures, respectively. Magnetic measurements indicate that the Fe and Co complexes have spontaneous magnetizations below the transition temperatures of 3.2 and 1.8 K, respectively.
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