Many chemists have attempted syntheses of extended π-electron network molecules because of the widespread interest in the chemistry, physics and materials science of such molecules and their potential applications. In particular, extended phenacene molecules, consisting of coplanar fused benzene rings in a repeating W-shaped pattern have attracted much attention because field-effect transistors (FETs) using phenacene molecules show promisingly high performance. Until now, the most extended phenacene molecule available for transistors was [8]phenacene, with eight benzene rings, which showed very high FET performance. Here, we report the synthesis of a more extended phenacene molecule, [9]phenacene, with nine benzene rings. Our synthesis produced enough [9]phenacene to allow the characterization of its crystal and electronic structures, as well as the fabrication of FETs using thin-film and single-crystal [9]phenacene. The latter showed a field-effect mobility as high as 18 cm2 V−1 s−1, which is the highest mobility realized so far in organic single-crystal FETs.
Field-effect transistors have been fabricated using [8]phenacene single-crystals, showing the maximumμvalue of 8.2 cm2V−1s−1. The CMOS inverter circuit has also been fabricated.
The effect of sheet‐ and film‐type electromagnetic noise suppressors on differential mode (DM) and common mode (CM) transmission characteristics in two parallel lines was investigated. Simple two parallel microstrip lines with a Co‐Zr‐Nb film were used as a test bench. The transmission characteristics of DM and CM were measured by four‐port network analyzer. The ferromagnetic resonance (FMR) and eddy current losses generated in the Co‐Zr‐Nb film were calculated by 3D full wave simulator, and the effects of these losses on the transmission characteristics were estimated. The results show that the transmission characteristics are different in DM and CM because the frequency characteristics of the losses are different according to the different FMR frequency in each mode. Furthermore, the feasibility of the application of the magnetic film as a frequency‐selective CM filter is demonstrated by using the difference in frequency characteristics of loss of DM and CM.
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