Birefringence measurements have been carried out on the Pb-doped silica hydrogels prepared under various magnetic fields up to 5T. The silica gels prepared at 5T were used as a medium of crystal growth of PbBr2, whose result implied the structural anisotropy; an aligned array of crystallites was obtained by transmission electron microscopy. While the samples prepared at 0, 1, and 3T have no birefringence, we found that the samples have negative birefringence on the order of magnitude 10 −6 as if the direction of the magnetic field is the optic axis of a uniaxal crystal. To the authors' knowledge, the birefringent silica hydrogels were obtained by gelation under magnetic field for the first time. Also, scanning microscopic light scattering experiments have been performed. The results indicate that the characteristic length distribution for birefringent samples is narrower than that for non-birefringent ones.
An integrated optic ammonia gas sensor using a graphene-covered silicon microring resonator is proposed. Ammonia gas adsorption increases the Fermi energy of graphene. The gas concentration is detected by the resonant-wavelength shift of the microring resonator. The NH 3 gas concentration from 0.5 to 1000 ppm is shown to be measured by the resonant wavelength from 1 551.75 to 1 551.27 nm. By applying voltage to the graphene, the Fermi energy is controlled to adjust the sensitivity and the range of detectable concentration.
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