High concentration of Mn atoms has been incorporated in the surface region of II-IV-V2 type chalcopyrite semiconductor CdGeP2. Photoluminescence spectrum at 20 K shows a peak around 3.2 eV, suggesting that the incorporation of Mn introduces an energy gap much higher than that of the host semiconductor (Eg=1.83 eV). Prominent magnetic hysteresis loops with coercivity of 0.5 kOe has been observed at room temperature. Magnetic force microscope (MFM) measurements reveal a stripe-shaped domain pattern on the top surface. Magneto-optical Kerr ellipticity spectrum measured at room temperature show a prominent peak at 1.7 eV and a broad tail up to 3.5 eV. We tentatively attribute the ferromagnetism to the double exchange interaction between Mn 2+ and Mn 3+ states due to the structural feature of II-IV-V2 type chalcopyrite compounds.

Reactions of the head-to-head 2-pyridonato-bridged cis-diammineplatinum(III) dinuclear complex having nonequivalent two platinum atoms, Pt(N(2)O(2)) and Pt(N(4)), with p-styrenesulfonate, 2-methyl-2-propene-1-sulfonate, 4-penten-1-ol, and 4-pentyn-1-ol were studied kinetically. Under the pseudo first-order reaction conditions that the concentration of the Pt(III) dinuclear complex is much smaller than that of olefin, a consecutive basically four-step reaction was observed: the olefin pi-coordinates preferentially to the Pt(N(2)O(2)) in the first step (step 1), followed by the second pi-coordination of another olefin molecule to the Pt(N(4)) (step 2). In the next step (step 3), the nucleophilic attack of water to the coordinated olefin triggers the pi-sigma bond conversion on the Pt(N(2)O(2)), and the second pi-bonding olefin molecule on the Pt(N(4)) is released. Finally, reductive elimination occurs to the alkyl group on the Pt(N(2)O(2)) to produce the alkyl compound (step 4). The first water substitution with olefin (step 1) occurs to the diaqua and aquahydroxo forms of the complex, whereas the second substitution (step 2) proceeds either on the coordinated OH(-) on the Pt(N(4)) (path a) or on the coordinatively unsaturated five-coordinate intermediate of the Pt(N(4)) (path b), in addition to the common substitution of H(2)O (path c). The reactions of p-styrenesulfonate and 2-methyl-2-propene-1-sulfonate proceed through paths b and c, whereas the reactions of 4-penten-1-ol and 4-pentyn-1-ol proceed through paths a and c. This difference reflects the difference of the trans effect and/or trans influence of the pi-coordinated olefins on the Pt(N(2)O(2)). The pentacoordinate state in path b is employed only by the sulfo-olefins, because these exert stronger trans effect. The steps 3 and 4 reflect the effect of the axial alkyl ligand (R) on the charge localization (R-Pt(IV)(N(2)O(2))-Pt(II)(N(4))) and delocalization (R-Pt(III)(N(2)O(2))-Pt(III)(N(4))-OH(2)); when R is p-styrenesulfonate having an electron withdrawing group, the charge localization in the dimer is less pronounced and the water molecule on the Pt(N(4)) atom is retained (R-Pt(III)(N(2)O(2))-Pt(III)(N(4))-OH(2)) in the intermediate state. In both routes, the alkyl group undergoes nucleophilic attack of water, and the oxidized products are released via reductive elimination.

Articles you may be interested inPreparation of Y0.5Bi2.5Fe5O12 films on glass substrates using magnetic iron garnet buffer layers by metalorganic decomposition method J. Appl. Phys. 113, 17A926 (2013); 10.1063/1.4798480Comment on "The role of Bi3+ ions in magneto-optic Ce and Bi comodified epitaxial iron garnet films" [Appl.Development of liquid phase epitaxy-grown (Bi, Gd, Lu)-substituted thin-film iron garnets Epitaxial ͑Y,Bi͒ 3 ͑Fe, Ga͒ 5 O 12 garnet thin films have been prepared on Gd 3 Ga 5 O 12 (111) substrates by a metal-organic decomposition (MOD) method using carboxylic acids. The chemical compositions of the films prepared in this study are Y 2 BiFe 5 O 12 (YBFO), Y 3 Fe 4 GaO 12 (YFGO), and Y 2 BiFe 4 GaO 12 (YBFGO). Epitaxy of these films was confirmed by x-ray diffraction and Rutherford backscattering (RBS) measurements. Full width of half maximum values of the 444 diffraction peaks of YFGO and YBFGO were 0.4°and 0.04°, respectively. RBS channeling was clearly observed for the YFGO film with a minimum yield min along the [111] direction of ϳ7.5%. These garnet films could also be reproducibly obtained by the MOD method without any deterioration in the MOD solutions over two years.

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In this work, we present a systematic study of optical and magneto-optical properties of Y 3-x Bi x Fe 5 O 12 thin films with various Bi concentrations (x = 1.5, 2, 2.5, 3) prepared by Metal Organic Decomposition on Gd 3 Ga 5 O 12 (100) substrates. We used magneto-optical spectroscopy and spectroscopic ellipsometry. Spectral dependence of complex refraction indexes obtained from ellipsometric measurements revealed increasing optical absorption with increasing Bi concentrations. Faraday and Kerr magneto-optical spectra measured in the photon energy range from 1.5 to 5.5 eV clearly demonstrated that the increasing Bi concentration enhances the spin-orbit coupling and influences the magnetooptical effect. Using the magneto-optical and ellipsometric experimental data we deduced a spectral dependence of complete permittivity tensor in a wide spectral range. Comparison of obtained results with the results reported on Liquid Phase Epitaxy bulk-like garnets with small Bi concentrations showed agreement and confirmed a high optical and magneto-optical quality of investigated films.