We report the precipitation and control of metal nanoparticles inside transparent glasses. An Ag ϩ -doped silicate glass sample was first irradiated by using an 800 nm femtosecond laser at room temperature and then annealed at 550°C. The area near the focal point of the laser beam became gray after laser irradiation and yellow after further annealing at 550°C for 10 min. Absorption and electron spin resonance spectra of the glass sample showed that a portion of silver ions near the focused part of the laser beam inside the glass were reduced to silver atoms after the laser irradiation. These silver atoms aggregated to form nanoparticles after further annealing at temperatures above 500°C. A mechanism is suggested that consists of multiphoton reduction, which is induced by the fundamental light of the laser beam and supercontinuum white light, and diffusion of silver atoms driven by heat energy to form nanoparticles. The observed phenomenon may have promising applications for the fabrication of three-dimensional multicolored images inside a transparent material and for integrative micro-optical switches.

Accumulation of thermal energies by highly repeated irradiation of femtosecond laser pulses inside a glass induces the heat-modification whose volume is much larger than that of the photoexcited region. It has been proposed that the heat-modification occurs in the region in which the temperature had overcome a threshold temperature during exposure of laser pulses. In order to understand the mechanism of the heat-modification, we investigated the temperature distribution during laser exposure and the threshold temperature by analyzing the volume of the modification based on a thermal diffusion model. We found that the threshold temperature becomes lower with increasing laser exposure time. The dependence of the threshold temperature on the laser exposure time was explained by the deformation mechanism based on the temperature-dependent viscosity and viscoelastic behavior of a glass under a stress loading by thermal expansion. The deformation mechanism also could simulate a tear-drop shape of a heat-modification by simultaneous double-beams' irradiation and the distribution of birefringence in a heat-modification. The mechanism proposed in this study means that the temperature-dependence of the viscosity of a glass should be essential for predicting and controlling the heat-modification.

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We have investigated the deformation mechanism of ruby in a microscopic area using a femtosecond laser having a pulse width, wavelength, and repetition rate of 238 fs, 780 nm, and 1 kHz, respectively. Transmission electron microscope observation revealed that a specific oblique pattern originating from cracks having a width of approximately 10 nm formed at the focal point. The peak shift of ruby fluorescence indicated the existence of a residual stress of 0.11 GPa at the irradiated area. Considering the pattern and magnitude of the residual stress at the focal point, we suggest that the crack propagated along the rhombohedral planes and the planes by laser irradiation.

Room temperature bonding of sapphire-sapphire and sapphire-metal substrates was achieved in Air using Au films. This bonding technique can support expansion of the potential applications of sapphire in diverse industries.