Glass–polymer composite electrolytes of high lithium ion conducting oxysulfide glass and the comb-shaped poly(oxyethylene) polymer (TEC-19) were prepared. The conductivity of the composite with 2 vol% TEC-19 doped with LiClO4 was 1 × 10−3 at 100 °C and 3 × 10−5 S cm−1 at 30 °C. The composite exhibited a 4 V stable potential window versus Li+/Li.
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