CuO nanoparticles have been extensively used as a photocatalyst because of their superior activity, selectivity and stability properties. The catalytic efficiency of these oxide nanoparticles can be improved by varying the size and shape of nanoparticles. Here, we report the synthesis of different shaped CuO nanoparticles and their impregnation on TiO2. Optical analysis revealed that a considerable red shift (420 nm to 550 nm) in absorption spectra of CuO–TiO2 nanocomposites was observed compared to bare CuO nanoparticles. DLS measurements showed that the average hydrodynamic size of CuO nanostars was increased from 160 nm to 584 nm after deposition on TiO2. These nanocomposites were examined for photocatalytic degradation of methyl orange under sunlight radiation. It was observed that CuO–TiO2 nanostars exhibited superior photocatalytic efficiency compared to CuO-nanoneedles, nanocrumbles and bare CuO nanoparticles. The CuO nanoparticles act as co-catalyst on the surface of TiO2 and alter the physicochemical properties of TiO2. The higher activity arises due to the fact that the doping of CuO reduces the recombination of charge carries (e−−h+) and creates the intra-gap states which result in higher absorption of light radiations. Therefore, CuO nanoparticles impregnated on TiO2 found to be an effective and ideal catalyst for the photodegradation of methyl orange dye.

The conformational landscape of the monohydrated complex of N-allylmethylamine (AMA–w) was investigated for the first time using rotational spectroscopy from 8–20 GHz and quantum chemistry calculations. From a total of...

The conformational landscape of diallyl ether (DAE) and diallyl sulfide (DAS) were investigated for the first time using rotational spectroscopy from 6–20 GHz supported by quantum mechanical calculations. A significant...

The highly variable conformational landscape of N-allylmethylamine (AMA) was investigated using Fourier transform microwave spectroscopy aided by high-level theoretical calculations to understand the energy relationship governing the interconversion between nine stable conformers. Spectroscopically, transitions belonging to four low energy conformers were identified and their hyperfine patterns owing to the 14 N quadrupolar nucleus were unambiguously resolved. The rotational spectrum of the global minimum geometry, conformer I, shows an additional splitting associated with a tunneling motion through an energy barrier interconnecting its enantiomeric forms. A two-step tunneling trajectory is proposed by finding transition state structures corresponding to the allyl torsion and NH inversion. Natural bond orbital and noncovalent interaction analyses reveal that an interplay between steric and hyperconjugative effects rules the conformational preferences of AMA.