A set of experimental measurements of scattering films and organic light emitting devices (OLEDs) is presented. We measure the reflectance, transmission, and emission characteristics of scattering media and OLED devices separately, and use this data as input into a simple radiative transfer model to predict the effect of light scattering on OLED light output. We find quantitative agreement between the radiative transfer model predictions and experimental results. We find that the introduction of volumetric scattering mechanisms increases the output of OLEDs by as much as 40%, which corresponds to over 70% of the light within a typical glass substrate being coupled to air.

We demonstrate high performance organic light-emitting diodes (OLEDs) fabricated via a vacuum-free, direct lamination process. The OLEDs were made by laminating an anode component to a separately engineered cathode component using a roll laminator. We further present a solution-based chemical n-doping strategy to enable efficient electron injection from an inert cathode into polymeric organic semiconductors. The n-doping strategy is demonstrated by chemically reducing a conjugated light-emitting polymer with an alkali metal in an organic solvent. The metal reduced conjugated polymer, when employed as an electron injection layer, yields laminated OLEDs with efficiency comparable to conventionally fabricated devices utilizing a vacuum-deposited, reactive metal cathode. These designs and techniques should enable applications such as lighting where extremely low cost device fabrication is required.

Slot die coating is a cost‐effective, scalable process for applying continuous organic layers in OLED displays. Uniform submicron coatings can be obtained on patterned OLED backplanes from low viscosity fluids. Coating and drying defects can be reduced by adjusting fluid properties, e.g., surface tension, viscosity and concentration.

A series of bis-(diphenylamino)diphenylpolyenes containing up to eight double bonds has been synthesized, both as parent model compounds, and functionalized for attachment as pendant chromophores. Oxidative doping of these new materials yields exceptionally stable bipolaronlike dications, even at the triene level. These new materials show promise as bimechanistic optical limiters by reverse saturable absorption and by 2-photon absorption.

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