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Large fractions of metals are missing from the observable gas-phase in the interstellar medium (ISM) because they are incorporated into dust grains, a phenomenon called dust depletion. The study of the depletion of metals into dust grains in the ISM is important to investigate the origin and evolution of metals and cosmic dust. Here we aim at characterizing the dust depletion of several metals from the Milky Way to distant galaxies. We collect measurements of ISM metal column densities from absorption-line spectroscopy in the literature, and in addition, we determine Ti and Ni column densities from a sample of 70 damped Lyman-α absorbers (DLAs) towards quasars, observed at high spectral resolution with the Very Large Telescope (VLT) Ultraviolet and Visual Echelle Spectrograph (UVES). We use ISM relative abundances to estimate the dust depletion of 18 metals (C,

The study of the properties of galaxies in the first billion years after the Big Bang is one of the major topics of current astrophysics. Optical and near-infrared spectroscopy of the afterglows of long gamma-ray bursts (GRBs) provides a powerful diagnostic tool to probe the interstellar medium (ISM) of their host galaxies and foreground absorbers, even up to the highest redshifts. We analyze the VLT/X-shooter afterglow spectrum of GRB 210905A, triggered by the Neil Gehrels Swift Observatory, and detect neutral hydrogen, low-ionization, high-ionization, and fine-structure absorption lines from a complex system at z = 6.3118, which we associate with the GRB host galaxy. We use them to study the ISM properties of the host system, revealing the metallicity, kinematics, and chemical abundance pattern of its gas along the GRB line of sight. We also detect absorption lines from at least two foreground absorbers at z = 5.7390 and z = 2.8296. The total metallicity of the z ∼ 6.3 system is [M/H]tot = −1.72 ± 0.13, after correcting for dust depletion and taking α-element enhancement into account, as suggested by our analysis. This is consistent with the values found for the other two GRBs at z ∼ 6 with spectroscopic data showing metal absorption lines (GRB 050904 and GRB 130606A), and it is at the higher end of the metallicity distribution of quasar damped Lyman-α systems (QSO-DLAs) extrapolated to such a high redshift. In addition, we determine the overall amount of dust and dust-to-metal mass ratio (DTM) ([Zn/Fe]fit = 0.33 ± 0.09 and DTM = 0.18 ± 0.03). We find indications of nucleosynthesis due to massive stars and, for some of the components of the gas clouds, we find evidence of peculiar nucleosynthesis, with an overabundance of aluminum (as also found for GRB 130606A). From the analysis of fine-structure lines, we determine distances of several kiloparsecs for the low-ionization gas clouds closest to the GRB. Those are farther distances than usually found for GRB host absorption systems, possibly due to the very high number of ionizing photons produced by the GRB that could ionize the line of sight up to several hundreds of parsecs. Using the HST/F140W image of the GRB field, we show the GRB host galaxy (with a possible afterglow contamination) as well as multiple objects within 2″ from the GRB position. We discuss the galaxy structure and kinematics that could explain our observations, also taking into account a tentative detection of Lyman-α emission at z = 6.3449 (∼1200 km s−1 from the GRB redshift in velocity space), and the observational properties of Lyman-α emitters at very high redshift. This study shows the amazing potential of GRBs to access detailed information on the properties (metal enrichment, gas kinematic, dust content, nucleosynthesis...) of very high-redshift galaxies, independently of the galaxy luminosity. Deep spectroscopic observations with VLT/MUSE and JWST will offer the unique possibility of combining the information presented in this paper with the properties of the ionized gas, with the goal of better understanding how galaxies in the reionization era form and evolve.

The chemical composition of gas in galaxies can be measured in great detail using absorption spectroscopy. By studying gas in galaxies in this way, it is possible to investigate small and faint galaxies, which are the most numerous in the universe. In particular, the chemical distribution of gas in absorbing systems gives us insight into cycles of gas in and around galaxies. In this work we study chemical enrichment within 64 damped Lyman-α absorption systems (DLAs) for redshifts in the range 1.7 < z < 4.2. We use high-resolution spectra from VLT/UVES to infer dust depletion from relative abundances of several metals. Specifically, we performed a component-by-component analysis within DLAs, and characterised variations in their chemical enrichment. Unlike hydrogen, the metal columns can be characterised according to their individual components. We used them to derive the dust depletion, which is an indicator of chemical enrichment. Our main results are as follows. Firstly, we find that some DLAs are chemically diverse within themselves (with the measure of dust depletion [Zn/Fe]fit ranging up to 0.62 dex within a single system), suggesting that the absorbing gas within these galaxies is chemically diverse. Secondly, although we do not find a clear trend of decreasing dust depletion with redshift, we do see that the most chemically enriched systems are at lower redshifts. We also observe evidence for dust-poor components at all redshifts, which may be due to the accretion of pristine gas onto galaxies. By combining the chemical and kinematic properties of the individual gas components, we observe potential signatures of infalling gas with low depletion at velocities below ∼100 km s−1, and outflows with high depletion and velocities of ∼600 km s−1. Finally, we find over-abundances of α-elements (an enhancement of ∼0.3 dex) and under-abundances of Mn in several gas components, which is likely a signature of core-collapse supernovae nucleosythesis in the ISM. We observe these effects mostly at lower levels of chemical enrichment.

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