A simple approach for growing porous electrochemically reduced graphene oxide (pErGO) networks on copper wire, modified with galvanostatically deposited copper foam is demonstrated. The as-prepared pErGO networks on the copper wire are directly used to fabricate solid-state supercapacitor. The pErGO-based supercapacitor can deliver a specific capacitance (Csp) as high as 81±3 F g−1 at 0.5 A g−1 with polyvinyl alcohol/H3PO4 gel electrolyte. The Csp per unit length and area are calculated as 40.5 mF cm−1 and 283.5 mF cm−2, respectively. The shape of the voltammogram retained up to high scan rate of 100 V s−1. The pErGO-based supercapacitor device exhibits noticeably high charge-discharge cycling stability, with 94.5% Csp retained even after 5000 cycles at 5 A g−1. Nominal change in the specific capacitance, as well as the shape of the voltammogram, is observed at different bending angles of the device even after 5000 cycles. The highest energy density of 11.25 W h kg−1 and the highest power density of 5 kW kg−1 are also achieved with this device. The wire-based supercapacitor is scalable and highly flexible, which can be assembled with/without a flexible substrate in different geometries and bending angles for illustrating promising use in smart textile and wearable device.
Carbonaceous materials with high surface area and a sheet-like structure promote fast ion-transport kinetics, making them an ideal choice to be used in supercapacitors. Few-layer graphene (FLG)-like nanosheets with abundance of micro as well as mesopores are achieved via mechanical exfoliation method from an agricultural waste biomass: peanut shell (PS). A well-known elementary method of probe-sonication, for the achievement of FLG sheets from renewable sources, is introduced in this study for the very first time. The Peanut shell-derived FLG (PS-FLG) possesses remarkably high specific surface area (2070 m2 g−1) with a sufficiently large pore volume of 1.33 cm3 g−1. For the fabrication of a binder-free supercapacitor, the PS-FLG-based electrodes exhibited a high specific capacity of 186 F g−1 without the use of any binder in 1 M H2SO4 as supporting electrolyte. The highest energy density of 58.125 W h Kg−1 and highest power density of 37.5 W Kg−1 was achieved by the material. Surprisingly, the working potential increased to 2.5 V in an organic electrolyte leading to an obvious increase in the energy density to 68 W h Kg−1. Solid-state-supercapacitor was fabricated with this material for the possible use of low-cost, high energy promising energy storage device.
Interconnected conducting porous graphene as supercapacitive material as well as current collector for integrated metal-free microsupercapacitor (MSC) having ultra-long cycle life and outstanding capacitive performance.
A facile route for electrochemical synthesis of single-phase Ni5P4 on copper foam results in a core-shell nanostructures catalyst for the efficient generation of hydrogen with a very less overpotential and excellent stability at high current density.
The
rational design of electronically tuned transition-metal-doped conductive
carbon nanostructures has emerged as a potential substitution of a
platinum-group-metal (PGM)-free electrocatalyst for oxygen reduction
reaction (ORR). We report here a universal strategy using a one-step
thermal polymerization reaction for transition-metal-doped graphitic
carbon nitride (g-C3N4) without any conductive
carbon support as a highly efficient ORR electrocatalyst. X-ray absorption
spectroscopy evidences the presence of Fe–Nx active
sites with a possible three-coordinated Fe atom with N atoms. The
as-prepared Fe-g-C3N4 with improved surface
area, graphitic nature, and conductive carbon framework exhibits a
superior electrochemical performance toward ORR activity in an alkaline
medium. Interestingly, it displays a 0.88 V (vs reversible hydrogen
electrode, RHE) half-wave potential (E
1/2) with a four-electron-transfer pathway and excellent stability outperforming
platinum/carbon (Pt/C) in an alkaline medium. More impressively, when
the Fe-g-C3N4 catalyst is used as a cathode
material in a zinc–air battery, it presents a higher peak power
density (148 mW cm–2) than Pt/C (133 mW cm–2), which further established the importance of the low-cost material
synthesis approach toward the development of an earth-abundant PGM-free
catalyst for fuel-cell and air battery fabrication.
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