Highly porous nanostructures with large surface areas are typically employed for electrical double-layer capacitors to improve gravimetric energy storage capacity; however, high surface area carbon-based electrodes result in poor volumetric capacitance because of the low packing density of porous materials. Here, we demonstrate ultrahigh volumetric capacitance of 521 F cm−3 in aqueous electrolytes for non-porous carbon microsphere electrodes co-doped with fluorine and nitrogen synthesized by low-temperature solvothermal route, rivaling expensive RuO2 or MnO2 pseudo-capacitors. The new electrodes also exhibit excellent cyclic stability without capacitance loss after 10,000 cycles in both acidic and basic electrolytes at a high charge current of 5 A g−1. This work provides a new approach for designing high-performance electrodes with exceptional volumetric capacitance with high mass loadings and charge rates for long-lived electrochemical energy storage systems.
Air
filtration materials (AFMs) have gradually become a research
hotspot on account of the increasing attention paid to the global
air quality problem. However, most AFMs cannot balance the contradiction
between high filtration efficiency and low pressure drop. Electrospinning
nanofibers have a large surface area to volume ratio, an adjustable
porous structure, and a simple preparation process that make them
an appropriate candidate for filtration materials. Therefore, electrospun
nanofibers have attracted increased attention in air filtration applications.
In this paper, first, the preparation methods of high-performance
electrospun air filtration membranes (EAFMs) and the typical surface
structures and filtration principles of electrospun fibers for air
filtration are reviewed. Second, the research progress of EAFMs with
multistructures, including nanoprotrusion, wrinkled, porous, branched,
hollow, core–shell, ribbon, beaded, nets structure, and the
application of these nanofibers in air filtration are summarized.
Finally, challenges with the fabrication of EAFMs, limitations of
their use, and trends for future developments are presented.
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