MXenes are a family of two-dimensional multifunctional materials in a rapid development phase since their discovery in 2011. MXenes possess excellent features like high conductivity and surface area, improved mechanical properties, hydrophilicity, and ability to tune the surface properties with modifying functional groups. These features make MXenes suitable candidates for a wide range of applications, including biomedical and energy storage. This review is focused on various types of MXenes which are recently reported for sensor applications. The current scenario regarding fabrication and properties of MXenes are initially described, followed by a discussion of their applications as piezoresistive and biochemical sensors. This involves mechanical strain detection and detection of biomolecules, biomarkers, and drug molecules relevant to biomedical applications. Finally, the future perspectives are briefly discussed, which will help the researchers identify the limitations for the current scenario and develop new strategies that focus on developing novel, efficient and sensitive MXene based sensors.
Silver
vanadate nanorods (β-AgVO3) with silver
nanoparticles (Ag-NPs) decorated on the surface of the rods were synthesized
by using simple hydrothermal technique and later anchored onto nitrogen-doped
reduced graphene oxide (N-rGO) to make a novel nanocomposite. Experimental
analyses were carried out to identify the electronic configuration
by X-ray diffraction analysis, Fourier transform infrared spectroscopy,
and X-ray photoelectron spectroscopy analysis, which revealed monoclinic
patterns of the C12/m1 space group
with Wulff construction forming beta silver vanadate (β-AgVO3) crystals with optical density and phase transformations.
Ag nucleation showed consistent results with metallic formation and
electronic changes occurring in [AgO5] and [AgO3] clusters. Transmission electron microscopy and field-emission scanning
electron microscopy with elemental mapping and EDX analysis of the
morphology reveals the nanorod structure for β-AgVO3 with AgNPs on the surface and sheets for N-rGO. Additionally, a
novel electrochemical sensor is constructed by using Ag/AgVO3/N-rGO on screen-printed carbon paste electrodes for the detection
of antiviral drug levofloxacin (LEV) which is used as a primary antibiotic
in controlling COVID-19. Using differential pulse voltammetry, LEV
is determined with a low detection limit of 0.00792 nm for a linear
range of 0.09–671 μM with an ultrahigh sensitivity of
152.19 μA μM–1 cm–2. Furthermore, modified electrode performance is tested by real-time
monitoring using biological and river samples.
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