Experiments were conducted to study peculiarities of drop impact onto electrospun polymer nanofiber mats. The nanofiber cross-sectional diameters were of the order of several hundred nanometers, the pore sizes in the mats of about several micrometers, and the mat thicknesses of the order of 200 microm. Polyacrylonitrile (PAN), a polymer which is partially wettable by water, was used to electrospin nanofiber mats. The experiments revealed that drop impact onto nanotextured surfaces of nanofiber mats produce spreading similar to that on the impermeable surfaces. However, at the end of the spreading stage, the contact line is pinned and drop receding is prevented. At higher impact velocities, prompt splashing events with formation of tiny drops were observed. It was shown that the splash parameter K(d) = We(1/2) Re(1/4) (with We and Re being the Weber and Reynolds numbers, respectively) previously used to characterize the experiments with drop impact onto smooth impermeable dry substrates can be also used to describe the onset of splash on substrates coated by nanofiber mats. However its threshold value K(ds) (in particular, corresponding to the minimal impact velocity leading to generation of secondary droplets) for the nanotextured surfaces is higher than that for dry flat substrates. In addition, water penetration and spreading inside wettable nanofiber mats after drop impact was elucidated and quantified. The hydrodynamics of drop impact onto nanofiber mats is important for understanding effective spray cooling through nanofiber mats, recently introduced by the same group of authors.
Ceramic foams in the system Si-O-C, possessing different bulk densities and morphologies, were obtained from preceramic polymers using two different direct foaming approaches. The electric properties of the foams were varied by adding suitable fillers to the precursor mixtures in amounts up to 80 wt%. The electrical conductivity of the foams was varied by several orders of magnitude. The effects of the type of filler and preceramic polymer (methylsiloxane or methylphenylsiloxane resins), as well as the used filler precursor, on the properties of the ceramic foams were investigated.
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