This study aimed to investigate the effects of blend composition on packaging-related properties of poly(lactic acid) (PLA) and low density polyethylene (LDPE) blown films. Blend films with PLA contents of 5-20 wt% were produced and compared. Scanning electron micrographs of cross-sectional cryofractured surfaces of the blend films revealed that in situ fibre-reinforced composites were obtained. Viscosity ratio of the polymer components of ca 1 confirmed that fibre formation was favourable for this blend system. PLA microdomains were dispersed throughout the film in forms of long fibres (length-to-diameter ratio > 100) and ribbons. The number of fibres and ribbons increased with an increase of PLA content. Critical content of PLA was found to be 20 wt% for effective improvement of both moduli and gas barrier properties. Incorporation of poly[ethylene-co-(methyl acrylate)] compatibilizer showed minimal effect on PLA structure. However, it did improve moduli and O 2 barrier properties when sufficient amount (1.5 pph) was used in 10 wt% PLA/LDPE. In short, flow behaviour, ratio of polymer components and degree of compatibility together played intricate roles in the morphology and hence mechanical and transport properties of PLA/LDPE immiscible blends.where c is the percentage crystallinity in the sample, ΔH m is the melt enthalpy (J g −1 ) and ΔH ∞ is the melt enthalpy of a spherulite
A combination of room cooling and the use of thermal insulation materials to maintain okra quality under simulated storage and transportation was evaluated. Okra pods were packed in plastic baskets and either cooled at 18 °C or not cooled in a room for 2 h. After either room cooling or no cooling, the okra pods were covered with three different materials: (1) perforated linear low-density polyethylene (P-LLDPE), (2) two layers of heat-reflective sheet with thin nonwoven (HRS+TNNW), and (3) metalized foam sheet (MFS). Typical handling (TP) without cooling and covering with P-LLDPE was used as the control. The six treatments were conducted during simulated storage (18 °C for 48 h) and transportation (30 °C for 15 h). Results showed that MFS gave the best insulation properties (Qx and R-values), followed by HRS and TNNW. After room cooling, both HRS+TNNW and MFS materials delayed the time for pulp temperature to reach 18 °C (10 h), compared to P-LLDPE (2 h). TP presented the highest mass loss (17.8%) throughout simulated conditions, followed by cooling plus P-LLDPE (15.2%) and either of the thermal insulation materials with or without room cooling (3.6% to 5.2%), respectively. TP, cooling plus P-LLDPE, and no cooling plus MFS (44% to 56%) showed the highest percentage of decay, while cooling combined with both HRS+TNNW and MFS gave the lowest decay incidence (11–21%). Findings demonstrated that room cooling combined with HRS+TNNW had the highest efficiency for preserving cool temperature and reducing decay, compared to TP and room cooling plus MFS.
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