The development of Pt-supported catalysts
for a selective hydrocracking
and hydroisomerization of biohydrogenated diesel (BHD, n-C15–C18) to hydroprocessed renewable jet (HRJ) fuel (C9–C14)
was investigated. The different acidic supports (i.e., HY zeolite
with SiO2/Al2O3 ratios of 5.5 and
100 and amorphous silica–alumina supports) loaded with 0.5
wt % Pt content were prepared and tested for the catalytic conversion
of BHD to HRJ fuel. The Pt supported on HY zeolite with SiO2/Al2O3 ratio of 100 denoted as Pt/HY(100) catalyst
exhibited the highest jet fuel yield with high branched isomers due
to its good balance between metal and acid function. The effects of
the reaction temperature, reaction pressure, and liquid hourly space
velocity (LHSV) on the hydrocracking and hydroisomerization performance
were studied over Pt/HY(100) catalyst. The jet fuel yield was obtained
at maximum value of 33 wt % at 310 °C, 450 psig, LHSV of 1.0
h–1, and H2/BHD molar ratio of 30. A
stability test was also conducted over Pt/HY(100) catalyst for 160
h. No significant change in the catalytic activity and selectivity
during the test was observed, indicating the high stability of the
Pt/HY(100) catalyst.
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