The pursuit for sustainability in the papermaking industry calls for the elimination or reduction of synthetic additives and the exploration of renewable and biodegradable alternatives. Cellulose nanofibrils (CNFs), due to their inherent morphological and biochemical properties, are an excellent alternative to synthetic additives.These properties enable CNFs to improve the mechanical, functional and barrier properties of different types of paper. The nanosize diameter, micrometre length, semi-crystalline structure, high strength and modulus of CNFs has a direct influence on the mechanical properties of paper such as tensile index, burst index, Scott index, breaking length, tear index, Z-strength, E-modulus, strain at break, and tensile stiffness. This review details the role played by CNFs as an additive to improve strength properties of papers and the factors affecting the improvement in paper quality when CNFs are added as additives. The paper also includes techno-economic aspects of the process and identifies areas that need further research.
Wood is a versatile resource due to its inherent properties such as low density, good weight to strength ratio, unique hierarchical structure, microscale pores, and ease of processing, including its biodegradability and renewability. In the building and construction industry, engineered transparent wood (ETW) may serve as a sustainable replacement for glass which is environmentally unfriendly in its manufacture and application. Natural wood is non transparent due to its low optical transmittance, therefore, lignin and chromophores are modified or eliminated, and a polymer is infiltrated in order to achieve transparency. Engineered transparent wood (ETW) exhibits excellent optical properties (transmittance > 80%), high haze (haze > 70%), thermal insulation (thermal conductivity less than 0.23Wm−1 K−1), unique hierarchical structure, good loadbearing performance with tough failure behaviour (no shattering) and ductility. These properties extend wood applications to optical components such as solar cells, screens, windows, magnetic materials, and luminescent and decorative materials. This review details the production of ETW and how the wood density, wood thickness, wood type, wood direction, cellulose volume fraction, extent and type of delignification, polymer type, functionalisation of ETW affect the morphological, functional, optical, thermal, photodegradation and mechanical properties of ETW.
The pursuit for sustainability in the papermaking industry calls for the elimination or reduction of synthetic additives and the exploration of renewable and biodegradable alternatives. Cellulose nanofibrils (CNFs), due to their inherent morphological and biochemical properties, are an excellent alternative to synthetic additives. These properties enable CNFs to improve the mechanical, functional and barrier properties of different types of paper. The nanosize diameter, micrometre length, semi-crystalline structure, high strength and modulus of CNFs has a direct influence on the mechanical properties of paper such as tensile index, burst index, Scott index, breaking length, tear index, Z-strength, E-modulus, strain at break, and tensile stiffness. This review details the role played by CNFs as an additive to improve strength properties of papers and the factors affecting the improvement in paper quality when CNFs are added as additives. The paper also includes techno-economic aspects of the process and identifies areas that need further research.
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