No abstract

This research is firstly presented the thermal resistance of a ceramic backing made from metakaolin-based geopolymer for stainless steel welding. The general problems such as lack of fusion, hydrogen inclusion, porosity and corrosions of stainless steel welded specimens were found because, largely, stainless steel presents an affinity to gases as oxidation. Therefore, during welding, if these gases do not escape from the weld pool before solidification of weld metal, it results in porosities or hydrogen inclusions. In this case, it can be solved by properly using inert gas backing. The welder usually uses the steel backing plate with a gas release hole to support weld root and gas transmission for completed weld penetration and superior weld quality. Since the geopolymer shows a good property of thermal resistance, researchers are interested in using the ceramic backing made from geopolymer instead of the commercial ceramic backing. The ceramic backings from the geopolymer were designed merely in 3 types as follows: Narrow curved groove without gas release hole, narrow curved groove with gas release holes and wide curved groove with gas release holes. Consequently, two pieces of stainless steel were welded by gas tungsten arc welding and then the weld quality such as defects, porosity and root penetration of welded specimens was inspected. Moreover, the surface failure of ceramic backing after the welding process was also considered. The results revealed that ceramic backing from a geopolymer with wide curved groove and gas release holes gave completed penetration at the root when inspecting with non-destructive testing such as visual test, penetration test, and radiography test. It was concluded that the geopolymer could be used as ceramic backing in stainless steel welding by gas tungsten arc welding. Moreover, it could be used as backing for aluminum and steel welding as well.

Portland cement consists essentially of compounds of lime mixed with silica and alumina whereas zeolite is a kind of minerals containing high content of reactive silica and alumina. Therefore, there is a probability to apply zeolite in cement mortar in order to develop mortar properties. The purpose of this research was to study and analyze the efficiency of zeolite addition on properties of cement mortar. X-ray diffraction (XRD), universal testing machine (UTM) and scanning electron microscope (SEM) were used to characterize for mortar specimens. Mechanical property test was compressive strength according to ASTM C109 and carried out on 5 x 5 x 5 cm3 cube specimens at 1, 7 and 28 curing days. In this research, cement mortars were prepared by mixing type I Portland cement, fly ash, sand and zeolite. Zeolite was varied as 0, 0.25, 0.50 and 0.75 wt.% to cement and w/b (water to binder ratio) was 0.48. The results presented that the compressive strength of mortar with small amount of zeolite was improved since 1day age obviously comparing to that of mortar without zeolite. It was confirmed that zeolite would help strengthening the cement mortars at early strength.

Conventional cement production process emits tons of carbon dioxide gas which is one of the greenhouse gases that influence the environment across the world. Discovering the alternative construction material with the eco-friendly process and the performance similar to or greater than ordinary Portland cement has been attractive to find out. This research presented green construction materials or so-called geopolymers from metakaolin substituted by high calcium fly ash by 20, 40, 60, 80 and 100 wt%. Some researches reported that geopolymer produced from metakaolin and fly ash with alkali solution gave a great result, but usually, they used fly ash containing very low calcium component. Compressive strength at 3, 7 and 28 curing days and flowability were conducted. The compressive strength of geopolymers blended with high calcium fly ash was still developed as the curing day increased and revealed the highest at 28 days especially on MK40 (high calcium fly ash 60 wt%). Geopolymer pastes prepared with a higher amount of high calcium fly ash exhibited less viscous. It was proved that the high amount of high calcium fly ash could be applied and gave extraordinary compressive strength. Furthermore, X-ray diffraction and X-ray fluorescence were used to investigate chemical properties as well as microstructure by a scanning electron microscope. For phase analysis, the existence of oxides of calcium and sulfur in high calcium fly ash resulted in the formation of thenardite, calcite, portlandite and C-S-H phase associating with geopolymeric phase. Therefore, this research proposed the opportunity for geopolymer production by using abundant high calcium fly ash to raise the value of the industrial waste products and green alternative construction material compared with OPC.